Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds
Само за регистроване кориснике
2020
Аутори
Dodevski, VladimirJanković, Bojan Ž.
Radović, Ivana M.
Stojmenović, Marija
Čebela, Maria
Nikolić, Željka
Pagnacco, Maja C.
Panić, Ivan
Stanković, Miroslav
Чланак у часопису (Објављена верзија)
,
© 2019 The Author(s)
Метаподаци
Приказ свих података о документуАпстракт
In this work, plane tree seed-based activated carbons were characterized in detail for a variety of applications. The particularly important area of application would be in the artificial photosynthesis. After carbonization process of biomass precursor at 650°C, the resulting preliminary activated carbons were activated at various temperatures. The activated carbons were characterized by oxygen functionalities (a particularly important role has ester oxygen groups) which provide a unique microstructure. The chemical compositions of as-prepared activated carbons were analyzed through Fourier transform infrared and Raman spectra as well as gas chromatography–mass spectroscopy analysis, while morphology was observed by scanning electron microscopy analysis. Applied analysis showed that detected graphite mainly becomes uniformly nanocrystalline system. The current study also explored the applicability of carbon material obtained from plane tree seed as a potential gaseous adsorbent. The ch...aracterization showed that the tested material contains both mesopores and micropores, and this should be advantageous for the gas sorption process, since mesopores may provide low-resistant pathways for the diffusion of CO 2 molecules, while the micropores are the most suitable for trapping of CO 2 . The sorption process analysis (including adsorption/desorption isotherms behavior) shows indication that the rate-limiting step of CO 2 adsorption onto activated carbon is probably governed by diffusion-controlled process, especially at temperatures below 850°C.
Кључне речи:
Plane tree seeds biomass / eco-friendly material / activated carbon / pyrolysis / activation / characterizationsИзвор:
Energy and Environment, 2020, 31, 4, 583-612Финансирање / пројекти:
- Динамика нелинеарних физичкохемијских и биохемијских система са моделирањем и предвиђањем њихових понашања под неравнотежним условима (RS-MESTD-Basic Research (BR or ON)-172015)
- Наноструктурни функционални и композитни материјали у каталитичким и сорпционим процесима (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
- Функционални, функционализовани и усавршени нано материјали (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45005)
DOI: 10.1177/0958305X19880878
ISSN: 0958-305X
WoS: 000491749700001
Scopus: 2-s2.0-85074569785
Институција/група
VinčaTY - JOUR AU - Dodevski, Vladimir AU - Janković, Bojan Ž. AU - Radović, Ivana M. AU - Stojmenović, Marija AU - Čebela, Maria AU - Nikolić, Željka AU - Pagnacco, Maja C. AU - Panić, Ivan AU - Stanković, Miroslav PY - 2020 UR - https://vinar.vin.bg.ac.rs/handle/123456789/8900 AB - In this work, plane tree seed-based activated carbons were characterized in detail for a variety of applications. The particularly important area of application would be in the artificial photosynthesis. After carbonization process of biomass precursor at 650°C, the resulting preliminary activated carbons were activated at various temperatures. The activated carbons were characterized by oxygen functionalities (a particularly important role has ester oxygen groups) which provide a unique microstructure. The chemical compositions of as-prepared activated carbons were analyzed through Fourier transform infrared and Raman spectra as well as gas chromatography–mass spectroscopy analysis, while morphology was observed by scanning electron microscopy analysis. Applied analysis showed that detected graphite mainly becomes uniformly nanocrystalline system. The current study also explored the applicability of carbon material obtained from plane tree seed as a potential gaseous adsorbent. The characterization showed that the tested material contains both mesopores and micropores, and this should be advantageous for the gas sorption process, since mesopores may provide low-resistant pathways for the diffusion of CO 2 molecules, while the micropores are the most suitable for trapping of CO 2 . The sorption process analysis (including adsorption/desorption isotherms behavior) shows indication that the rate-limiting step of CO 2 adsorption onto activated carbon is probably governed by diffusion-controlled process, especially at temperatures below 850°C. T2 - Energy and Environment T1 - Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds VL - 31 IS - 4 SP - 583 EP - 612 DO - 10.1177/0958305X19880878 ER -
@article{ author = "Dodevski, Vladimir and Janković, Bojan Ž. and Radović, Ivana M. and Stojmenović, Marija and Čebela, Maria and Nikolić, Željka and Pagnacco, Maja C. and Panić, Ivan and Stanković, Miroslav", year = "2020", abstract = "In this work, plane tree seed-based activated carbons were characterized in detail for a variety of applications. The particularly important area of application would be in the artificial photosynthesis. After carbonization process of biomass precursor at 650°C, the resulting preliminary activated carbons were activated at various temperatures. The activated carbons were characterized by oxygen functionalities (a particularly important role has ester oxygen groups) which provide a unique microstructure. The chemical compositions of as-prepared activated carbons were analyzed through Fourier transform infrared and Raman spectra as well as gas chromatography–mass spectroscopy analysis, while morphology was observed by scanning electron microscopy analysis. Applied analysis showed that detected graphite mainly becomes uniformly nanocrystalline system. The current study also explored the applicability of carbon material obtained from plane tree seed as a potential gaseous adsorbent. The characterization showed that the tested material contains both mesopores and micropores, and this should be advantageous for the gas sorption process, since mesopores may provide low-resistant pathways for the diffusion of CO 2 molecules, while the micropores are the most suitable for trapping of CO 2 . The sorption process analysis (including adsorption/desorption isotherms behavior) shows indication that the rate-limiting step of CO 2 adsorption onto activated carbon is probably governed by diffusion-controlled process, especially at temperatures below 850°C.", journal = "Energy and Environment", title = "Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds", volume = "31", number = "4", pages = "583-612", doi = "10.1177/0958305X19880878" }
Dodevski, V., Janković, B. Ž., Radović, I. M., Stojmenović, M., Čebela, M., Nikolić, Ž., Pagnacco, M. C., Panić, I.,& Stanković, M.. (2020). Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds. in Energy and Environment, 31(4), 583-612. https://doi.org/10.1177/0958305X19880878
Dodevski V, Janković BŽ, Radović IM, Stojmenović M, Čebela M, Nikolić Ž, Pagnacco MC, Panić I, Stanković M. Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds. in Energy and Environment. 2020;31(4):583-612. doi:10.1177/0958305X19880878 .
Dodevski, Vladimir, Janković, Bojan Ž., Radović, Ivana M., Stojmenović, Marija, Čebela, Maria, Nikolić, Željka, Pagnacco, Maja C., Panić, Ivan, Stanković, Miroslav, "Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds" in Energy and Environment, 31, no. 4 (2020):583-612, https://doi.org/10.1177/0958305X19880878 . .