Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization
Само за регистроване кориснике
2020
Аутори
Dodevski, VladimirPagnacco, Maja C.
Radović, Ivana M.
Rosić, Milena
Janković, Bojan Ž.
Stojmenović, Marija
Mitić, Vojislav V.
Чланак у часопису (Објављена верзија)
,
Elsevier
Метаподаци
Приказ свих података о документуАпстракт
The aim of this research was to obtain a carbon solid residue by the carbonization process of biomass in an inert atmosphere which, through physical activation and chemical treatment (using TEOS - tetraethyl orthosilicate) would allow creation of highly porous and spatially distinct ordered bio-SiC ceramics. The results of carbonization experiments at several operating temperatures and activation of carbons with multiple-cycle treatments TEOS clearly showed the possibility of obtaining SiC nano-structures, after performing the carbothermal reduction at 1400 °C. The increase in the activation temperature and the duration time starts the development of the SiC particles inside the porous structure. The XRPD analysis showed that the major SiC polytype has cubic SiC (β-SiC) structure and remainder is hexagonal SiC polytypic (α-SiC) structure. It was established that the carbons obtained from carbonization of the Platanus orientalis L. plane tree fruit (PTF) precursor and activated at 850 °...C with longer holding times (1 and 2 h) exhibit β-SiC (cubic) nano-wires. A possible nano-wires increment mechanism was suggested. The obtained results represent significant contribution in understanding the process as well as the main characteristics of SiC nano-materials and their possible applications.
Кључне речи:
Wood-fruit precursor / Silica impregnation / Graphitic material / Stacking faults / β-SiC nano-wiresИзвор:
Materials Chemistry and Physics, 2020, 245, 122768-Финансирање / пројекти:
- Функционални, функционализовани и усавршени нано материјали (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45005)
- Развој опреме и процеса добијања полимерних композитних материјала са унапред дефинисаним функционалним својствима (RS-MESTD-Technological Development (TD or TR)-34011)
- Наноструктурни функционални и композитни материјали у каталитичким и сорпционим процесима (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
DOI: 10.1016/j.matchemphys.2020.122768
ISSN: 0254-0584
WoS: 000523626300006
Scopus: 2-s2.0-85079085607
Колекције
Институција/група
VinčaTY - JOUR AU - Dodevski, Vladimir AU - Pagnacco, Maja C. AU - Radović, Ivana M. AU - Rosić, Milena AU - Janković, Bojan Ž. AU - Stojmenović, Marija AU - Mitić, Vojislav V. PY - 2020 UR - https://vinar.vin.bg.ac.rs/handle/123456789/8817 AB - The aim of this research was to obtain a carbon solid residue by the carbonization process of biomass in an inert atmosphere which, through physical activation and chemical treatment (using TEOS - tetraethyl orthosilicate) would allow creation of highly porous and spatially distinct ordered bio-SiC ceramics. The results of carbonization experiments at several operating temperatures and activation of carbons with multiple-cycle treatments TEOS clearly showed the possibility of obtaining SiC nano-structures, after performing the carbothermal reduction at 1400 °C. The increase in the activation temperature and the duration time starts the development of the SiC particles inside the porous structure. The XRPD analysis showed that the major SiC polytype has cubic SiC (β-SiC) structure and remainder is hexagonal SiC polytypic (α-SiC) structure. It was established that the carbons obtained from carbonization of the Platanus orientalis L. plane tree fruit (PTF) precursor and activated at 850 °C with longer holding times (1 and 2 h) exhibit β-SiC (cubic) nano-wires. A possible nano-wires increment mechanism was suggested. The obtained results represent significant contribution in understanding the process as well as the main characteristics of SiC nano-materials and their possible applications. T2 - Materials Chemistry and Physics T1 - Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization VL - 245 SP - 122768 DO - 10.1016/j.matchemphys.2020.122768 ER -
@article{ author = "Dodevski, Vladimir and Pagnacco, Maja C. and Radović, Ivana M. and Rosić, Milena and Janković, Bojan Ž. and Stojmenović, Marija and Mitić, Vojislav V.", year = "2020", abstract = "The aim of this research was to obtain a carbon solid residue by the carbonization process of biomass in an inert atmosphere which, through physical activation and chemical treatment (using TEOS - tetraethyl orthosilicate) would allow creation of highly porous and spatially distinct ordered bio-SiC ceramics. The results of carbonization experiments at several operating temperatures and activation of carbons with multiple-cycle treatments TEOS clearly showed the possibility of obtaining SiC nano-structures, after performing the carbothermal reduction at 1400 °C. The increase in the activation temperature and the duration time starts the development of the SiC particles inside the porous structure. The XRPD analysis showed that the major SiC polytype has cubic SiC (β-SiC) structure and remainder is hexagonal SiC polytypic (α-SiC) structure. It was established that the carbons obtained from carbonization of the Platanus orientalis L. plane tree fruit (PTF) precursor and activated at 850 °C with longer holding times (1 and 2 h) exhibit β-SiC (cubic) nano-wires. A possible nano-wires increment mechanism was suggested. The obtained results represent significant contribution in understanding the process as well as the main characteristics of SiC nano-materials and their possible applications.", journal = "Materials Chemistry and Physics", title = "Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization", volume = "245", pages = "122768", doi = "10.1016/j.matchemphys.2020.122768" }
Dodevski, V., Pagnacco, M. C., Radović, I. M., Rosić, M., Janković, B. Ž., Stojmenović, M.,& Mitić, V. V.. (2020). Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization. in Materials Chemistry and Physics, 245, 122768. https://doi.org/10.1016/j.matchemphys.2020.122768
Dodevski V, Pagnacco MC, Radović IM, Rosić M, Janković BŽ, Stojmenović M, Mitić VV. Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization. in Materials Chemistry and Physics. 2020;245:122768. doi:10.1016/j.matchemphys.2020.122768 .
Dodevski, Vladimir, Pagnacco, Maja C., Radović, Ivana M., Rosić, Milena, Janković, Bojan Ž., Stojmenović, Marija, Mitić, Vojislav V., "Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization" in Materials Chemistry and Physics, 245 (2020):122768, https://doi.org/10.1016/j.matchemphys.2020.122768 . .