Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol
Само за регистроване кориснике
2020
Аутори
Carević, MilicaSavić, Tatjana D.
Abazović, Nadica
Mojović, Miloš D.
Novaković, Tatjana
Čomor, Mirjana
Чланак у часопису (Објављена верзија)
,
© 2019 Elsevier Ltd and Techna Group S.r.l.
Метаподаци
Приказ свих података о документуАпстракт
Pure and a series of Fe3+ doped zirconia nanopowders were synthesized combining colloidal chemistry and solvothermal method from organometallic precursors in order to correlate doping and properties of zirconia matrix. After annealing of washed nanopowders at 600 °C, detailed characterization was performed using X-ray diffraction, UV/Vis absorption and luminescence, infrared and electron paramagnetic spectroscopy, transmission electron microscopy and BET measurements. Zirconia samples had mixed monoclinic and tetragonal crystalline phase; increasing Fe3+ ions concentration was followed by increasing of tetragonal phase share. In the sample with highest Fe3+ concentration, hematite can be detected. Also, UV/Vis spectrophotometry showed that Fe3+ doping lowers effective band gap of zirconia matrix from 4.5 eV (bulk value) to 2.1 eV for doped/nanocomposite samples. EPR measurements proved presence of dopant and showed that isolated Fe3+ ions in zirconia matrix exist in both crystalline ph...ases; monoclinic and tetragonal (g 4.8 and g 4.27–4.2, respectively) surroundings. Zirconia samples were also successfully used as photocatalysts for photocatalytic degradation of 2, 4, 6, trichlorophenol. © 2019 Elsevier Ltd and Techna Group S.r.l.
Кључне речи:
Powders: chemical preparation / Electron microscopy / ZrO2 / Functional applicationИзвор:
Ceramics International, 2020, 46, 5, 6820-6827Финансирање / пројекти:
- Утицај величине, облика и структуре наночестица на њихова својства и својства нанокомпозита (RS-172056)
- Материјали редуковане димензионалности за ефикасну апсорпцију светлости и конверзију енергије (RS-45020)
DOI: 10.1016/j.ceramint.2019.11.175
ISSN: 0272-8842
WoS: 000515196800161
Scopus: 2-s2.0-85078751596
Колекције
Институција/група
VinčaTY - JOUR AU - Carević, Milica AU - Savić, Tatjana D. AU - Abazović, Nadica AU - Mojović, Miloš D. AU - Novaković, Tatjana AU - Čomor, Mirjana PY - 2020 UR - https://vinar.vin.bg.ac.rs/handle/123456789/8807 AB - Pure and a series of Fe3+ doped zirconia nanopowders were synthesized combining colloidal chemistry and solvothermal method from organometallic precursors in order to correlate doping and properties of zirconia matrix. After annealing of washed nanopowders at 600 °C, detailed characterization was performed using X-ray diffraction, UV/Vis absorption and luminescence, infrared and electron paramagnetic spectroscopy, transmission electron microscopy and BET measurements. Zirconia samples had mixed monoclinic and tetragonal crystalline phase; increasing Fe3+ ions concentration was followed by increasing of tetragonal phase share. In the sample with highest Fe3+ concentration, hematite can be detected. Also, UV/Vis spectrophotometry showed that Fe3+ doping lowers effective band gap of zirconia matrix from 4.5 eV (bulk value) to 2.1 eV for doped/nanocomposite samples. EPR measurements proved presence of dopant and showed that isolated Fe3+ ions in zirconia matrix exist in both crystalline phases; monoclinic and tetragonal (g 4.8 and g 4.27–4.2, respectively) surroundings. Zirconia samples were also successfully used as photocatalysts for photocatalytic degradation of 2, 4, 6, trichlorophenol. © 2019 Elsevier Ltd and Techna Group S.r.l. T2 - Ceramics International T1 - Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol VL - 46 IS - 5 SP - 6820 EP - 6827 DO - 10.1016/j.ceramint.2019.11.175 ER -
@article{ author = "Carević, Milica and Savić, Tatjana D. and Abazović, Nadica and Mojović, Miloš D. and Novaković, Tatjana and Čomor, Mirjana", year = "2020", abstract = "Pure and a series of Fe3+ doped zirconia nanopowders were synthesized combining colloidal chemistry and solvothermal method from organometallic precursors in order to correlate doping and properties of zirconia matrix. After annealing of washed nanopowders at 600 °C, detailed characterization was performed using X-ray diffraction, UV/Vis absorption and luminescence, infrared and electron paramagnetic spectroscopy, transmission electron microscopy and BET measurements. Zirconia samples had mixed monoclinic and tetragonal crystalline phase; increasing Fe3+ ions concentration was followed by increasing of tetragonal phase share. In the sample with highest Fe3+ concentration, hematite can be detected. Also, UV/Vis spectrophotometry showed that Fe3+ doping lowers effective band gap of zirconia matrix from 4.5 eV (bulk value) to 2.1 eV for doped/nanocomposite samples. EPR measurements proved presence of dopant and showed that isolated Fe3+ ions in zirconia matrix exist in both crystalline phases; monoclinic and tetragonal (g 4.8 and g 4.27–4.2, respectively) surroundings. Zirconia samples were also successfully used as photocatalysts for photocatalytic degradation of 2, 4, 6, trichlorophenol. © 2019 Elsevier Ltd and Techna Group S.r.l.", journal = "Ceramics International", title = "Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol", volume = "46", number = "5", pages = "6820-6827", doi = "10.1016/j.ceramint.2019.11.175" }
Carević, M., Savić, T. D., Abazović, N., Mojović, M. D., Novaković, T.,& Čomor, M.. (2020). Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol. in Ceramics International, 46(5), 6820-6827. https://doi.org/10.1016/j.ceramint.2019.11.175
Carević M, Savić TD, Abazović N, Mojović MD, Novaković T, Čomor M. Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol. in Ceramics International. 2020;46(5):6820-6827. doi:10.1016/j.ceramint.2019.11.175 .
Carević, Milica, Savić, Tatjana D., Abazović, Nadica, Mojović, Miloš D., Novaković, Tatjana, Čomor, Mirjana, "Effect of Fe3+ ion doping on photocatalytic ability of nanozirconia ceramic to degrade 2, 4, 6- trichlorophenol" in Ceramics International, 46, no. 5 (2020):6820-6827, https://doi.org/10.1016/j.ceramint.2019.11.175 . .