Analytical capability of the plasma induced by IR TEA CO2 laser pulses on copper-based alloys
Аутори
Momčilović, MilošCiganović, Jovan
Ranković, Dragan
Jovanović, Uroš D.
Stoiljković, Milovan
Savović, Jelena
Trtica, Milan
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The applicability of a nanosecond infrared (IR) transversely excited atmospheric (TEA) CO2 laser, operating at 10.6 mu m and 100 ns pulse length (initial spike), induced plasma under reduced air pressure for spectrochemical analysis of bronze and brass samples was investigated. The plasma consisted of two clearly distinguished and spatially separated regions and expanded to a distance of about 10 mm from the surface. The elemental composition of the samples was determined using a time-integrated space-resolved laser-induced plasma spectroscopic (TISR-LIPS) technique. Sharp and well-resolved spectral lines mostly atomic, and negligibly low background emission, were obtained from a plasma region 7 mm from the target surface. Good signal to background and signal to noise ratios were obtained. The estimated detection limits for the trace elements Mg, Fe, Al and Ca were in the order of 10 ppm in bronze and around 50 ppm in brass. Damage on the investigated samples induced by TEA CO2 laser r...adiation was negligible.
Кључне речи:
TEA CO2 laser / LIBS / copper-based alloysИзвор:
Journal of the Serbian Chemical Society, 2015, 80, 12, 1505-1513Финансирање / пројекти:
- Ефекти дејства ласерског зрачења и плазме на савремене материјале при њиховој синтези, модификацији и анализи (RS-MESTD-Basic Research (BR or ON)-172019)
DOI: 10.2298/JSC150416061M
ISSN: 0352-5139
WoS: 000367186500005
Scopus: 2-s2.0-84957604554
Колекције
Институција/група
VinčaTY - JOUR AU - Momčilović, Miloš AU - Ciganović, Jovan AU - Ranković, Dragan AU - Jovanović, Uroš D. AU - Stoiljković, Milovan AU - Savović, Jelena AU - Trtica, Milan PY - 2015 UR - https://vinar.vin.bg.ac.rs/handle/123456789/867 AB - The applicability of a nanosecond infrared (IR) transversely excited atmospheric (TEA) CO2 laser, operating at 10.6 mu m and 100 ns pulse length (initial spike), induced plasma under reduced air pressure for spectrochemical analysis of bronze and brass samples was investigated. The plasma consisted of two clearly distinguished and spatially separated regions and expanded to a distance of about 10 mm from the surface. The elemental composition of the samples was determined using a time-integrated space-resolved laser-induced plasma spectroscopic (TISR-LIPS) technique. Sharp and well-resolved spectral lines mostly atomic, and negligibly low background emission, were obtained from a plasma region 7 mm from the target surface. Good signal to background and signal to noise ratios were obtained. The estimated detection limits for the trace elements Mg, Fe, Al and Ca were in the order of 10 ppm in bronze and around 50 ppm in brass. Damage on the investigated samples induced by TEA CO2 laser radiation was negligible. T2 - Journal of the Serbian Chemical Society T1 - Analytical capability of the plasma induced by IR TEA CO2 laser pulses on copper-based alloys VL - 80 IS - 12 SP - 1505 EP - 1513 DO - 10.2298/JSC150416061M ER -
@article{ author = "Momčilović, Miloš and Ciganović, Jovan and Ranković, Dragan and Jovanović, Uroš D. and Stoiljković, Milovan and Savović, Jelena and Trtica, Milan", year = "2015", abstract = "The applicability of a nanosecond infrared (IR) transversely excited atmospheric (TEA) CO2 laser, operating at 10.6 mu m and 100 ns pulse length (initial spike), induced plasma under reduced air pressure for spectrochemical analysis of bronze and brass samples was investigated. The plasma consisted of two clearly distinguished and spatially separated regions and expanded to a distance of about 10 mm from the surface. The elemental composition of the samples was determined using a time-integrated space-resolved laser-induced plasma spectroscopic (TISR-LIPS) technique. Sharp and well-resolved spectral lines mostly atomic, and negligibly low background emission, were obtained from a plasma region 7 mm from the target surface. Good signal to background and signal to noise ratios were obtained. The estimated detection limits for the trace elements Mg, Fe, Al and Ca were in the order of 10 ppm in bronze and around 50 ppm in brass. Damage on the investigated samples induced by TEA CO2 laser radiation was negligible.", journal = "Journal of the Serbian Chemical Society", title = "Analytical capability of the plasma induced by IR TEA CO2 laser pulses on copper-based alloys", volume = "80", number = "12", pages = "1505-1513", doi = "10.2298/JSC150416061M" }
Momčilović, M., Ciganović, J., Ranković, D., Jovanović, U. D., Stoiljković, M., Savović, J.,& Trtica, M.. (2015). Analytical capability of the plasma induced by IR TEA CO2 laser pulses on copper-based alloys. in Journal of the Serbian Chemical Society, 80(12), 1505-1513. https://doi.org/10.2298/JSC150416061M
Momčilović M, Ciganović J, Ranković D, Jovanović UD, Stoiljković M, Savović J, Trtica M. Analytical capability of the plasma induced by IR TEA CO2 laser pulses on copper-based alloys. in Journal of the Serbian Chemical Society. 2015;80(12):1505-1513. doi:10.2298/JSC150416061M .
Momčilović, Miloš, Ciganović, Jovan, Ranković, Dragan, Jovanović, Uroš D., Stoiljković, Milovan, Savović, Jelena, Trtica, Milan, "Analytical capability of the plasma induced by IR TEA CO2 laser pulses on copper-based alloys" in Journal of the Serbian Chemical Society, 80, no. 12 (2015):1505-1513, https://doi.org/10.2298/JSC150416061M . .