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Ionization Energies of LinCln – 1 (n = 3, 4, and 5) Clusters Studied by the Modified Knudsen Cell Mass Spectrometry Method
dc.creator | Veljković, Filip M. | |
dc.creator | Vurdelja, Borislava D. | |
dc.creator | Rajčić, Boris | |
dc.creator | Veličković, Suzana | |
dc.date.accessioned | 2020-02-06T09:00:16Z | |
dc.date.available | 2020-02-06T09:00:16Z | |
dc.date.issued | 2019 | |
dc.identifier.issn | 0036-0244 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/8482 | |
dc.description.abstract | Abstract: In the present paper, ionization energies of LinCln – 1 (n = 3, 4, and 5) clusters were studied by means of the modified Knudsen cell mass spectrometry method, for the first time. The temperature dependence of the intensities of Li3Cl2 +, Li4Cl3 + and Li5Cl4 + ions were measured in the interval 1128–1616, 1126–1435, and 1947–2278 K, respectively. The following ionization energies were obtained: IE(Li3Cl2) = 4.51 ± 0.2 eV, IE(Li4Cl3) = 4.18 ± 0.2 eV, and IE(Li4Cl3) = 5.05 ± 0.2 eV. A good correlation of the experimental results with the theoretical adiabatic ionization energy is recognized. Results are confirmation that these clusters can be classified as “superalkalis.”. © 2019, Pleiades Publishing, Ltd. | en |
dc.language.iso | en | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172019/RS// | |
dc.rights | restrictedAccess | |
dc.source | Russian Journal of Physical Chemistry A | |
dc.subject | ionization energies | en |
dc.subject | Knudsen cell mass spectrometry | en |
dc.subject | LinCln – 1 | en |
dc.subject | “superalkali” clusters | en |
dc.title | Ionization Energies of LinCln – 1 (n = 3, 4, and 5) Clusters Studied by the Modified Knudsen Cell Mass Spectrometry Method | en |
dc.type | article | en |
dc.rights.license | ARR | |
dcterms.abstract | Величковић, Сузана; Рајчић, Борис; Вурдеља, Борислава Д.; Вељковић, Филип М.; | |
dc.rights.holder | © 2019, Pleiades Publishing, Ltd | |
dc.citation.volume | 93 | |
dc.citation.issue | 13 | |
dc.citation.spage | 2699 | |
dc.citation.epage | 2702 | |
dc.identifier.wos | 000511841100019 | |
dc.identifier.doi | 10.1134/S0036024419130302 | |
dc.citation.rank | M23 | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-85078050630 |
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