Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand
Само за регистроване кориснике
2019
Аутори
Perić, Marko R.Kyne, Sara H.
Gruden, Maja
Rodić, Marko V.
Jeremić, Dejan
Stanković, Dalibor M.
Brčeski, Ilija
Чланак у часопису (Објављена верзија)
,
© 2019, Springer-Verlag GmbH Austria, part of Springer Nature
Метаподаци
Приказ свих података о документуАпстракт
In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic.
Кључне речи:
Binuclear complex / Density functional theory / Magnetic properties / X-ray structure determinationИзвор:
Monatshefte fur Chemie, 2019, 150, 7, 1241-1248Финансирање / пројекти:
- Рационални дизајн и синтеза биолошки активних и координационих једињења и функционалних материјала, релевантних у (био)нанотехнологији (RS-MESTD-Basic Research (BR or ON)-172035)
- Корелација структуре и особина природних и синтетичких молекула и њихових комплекса са металима (RS-MESTD-Basic Research (BR or ON)-172017)
- Strengthening of the MagBioVin Research and Innovation Team for Development of Novel Approaches for Tumour Therapy based on Nanostructured Materials (EU-FP7-621375)
Напомена:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3317
DOI: 10.1007/s00706-019-02405-7
ISSN: 0026-9247
WoS: 000475674200009
Scopus: 2-s2.0-85068563687
Колекције
Институција/група
VinčaTY - JOUR AU - Perić, Marko R. AU - Kyne, Sara H. AU - Gruden, Maja AU - Rodić, Marko V. AU - Jeremić, Dejan AU - Stanković, Dalibor M. AU - Brčeski, Ilija PY - 2019 UR - https://vinar.vin.bg.ac.rs/handle/123456789/8381 AB - In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic. T2 - Monatshefte fur Chemie T1 - Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand VL - 150 IS - 7 SP - 1241 EP - 1248 DO - 10.1007/s00706-019-02405-7 ER -
@article{ author = "Perić, Marko R. and Kyne, Sara H. and Gruden, Maja and Rodić, Marko V. and Jeremić, Dejan and Stanković, Dalibor M. and Brčeski, Ilija", year = "2019", abstract = "In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic.", journal = "Monatshefte fur Chemie", title = "Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand", volume = "150", number = "7", pages = "1241-1248", doi = "10.1007/s00706-019-02405-7" }
Perić, M. R., Kyne, S. H., Gruden, M., Rodić, M. V., Jeremić, D., Stanković, D. M.,& Brčeski, I.. (2019). Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand. in Monatshefte fur Chemie, 150(7), 1241-1248. https://doi.org/10.1007/s00706-019-02405-7
Perić MR, Kyne SH, Gruden M, Rodić MV, Jeremić D, Stanković DM, Brčeski I. Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand. in Monatshefte fur Chemie. 2019;150(7):1241-1248. doi:10.1007/s00706-019-02405-7 .
Perić, Marko R., Kyne, Sara H., Gruden, Maja, Rodić, Marko V., Jeremić, Dejan, Stanković, Dalibor M., Brčeski, Ilija, "Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand" in Monatshefte fur Chemie, 150, no. 7 (2019):1241-1248, https://doi.org/10.1007/s00706-019-02405-7 . .