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Sorption of divalent heavy metal ions onto functionalized biogenic hydroxyapatite with caffeic acid and 3,4-dihydroxybenzoic acid
dc.creator | Smičiklas, Ivana D. | |
dc.creator | Lazić, Vesna M. | |
dc.creator | Živković, Ljiljana | |
dc.creator | Porobić, Slavica | |
dc.creator | Ahrenkiel, Scott Phillip | |
dc.creator | Nedeljković, Jovan | |
dc.date.accessioned | 2019-07-17T09:44:23Z | |
dc.date.available | 2019-07-17T09:44:23Z | |
dc.date.issued | 2019 | |
dc.identifier.issn | 1093-4529 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/8172 | |
dc.description.abstract | The sorption ability of biogenic hydroxyapatite (BHAP) towards heavy metal ions (Pb, Cu, Ni, Cd, and Zn) is compared with functionalized BHAP powders with caffeic acid (CA) and 3,4-dihydroxybenzoic acid (3,4-DHBA). The functionalization of the BHAP with either CA or 3,4-DHBA is indicated by the appearance of the colored powders due to the formation of the interfacial charge transfer (ICT) complexes. The detailed characterization of as-prepared and functionalized BHAP samples was performed using transmission electron microscopy, reflection spectroscopy, thermogravimetric analysis and determination of zeta potential. All three sorbents clearly displayed preferential sorption of Pb ions when the total concentration of multi-component equimolar solutions of heavy metal ions is high. It should be emphasized that the sorption capacity of functionalized BHAP with either CA or 3,4-BHAP was found to be higher, up to 60%, compared to as-prepared BHAP without the decrease of selectivity towards Pb ions. © 2019, © 2019 Taylor & Francis Group, LLC. | en |
dc.language.iso | en | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45020/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/43009/RS// | |
dc.rights | restrictedAccess | |
dc.source | Journal of Environmental Science and Health, Part A | |
dc.subject | Animal bones | en |
dc.subject | hydroxyapatite | en |
dc.subject | sorption | en |
dc.subject | heavy metal ions | en |
dc.subject | functionalization | en |
dc.subject | catechol derivatives | en |
dc.title | Sorption of divalent heavy metal ions onto functionalized biogenic hydroxyapatite with caffeic acid and 3,4-dihydroxybenzoic acid | en |
dc.type | article | en |
dc.rights.license | ARR | |
dcterms.abstract | Смичиклас, Ивана Д; Живковић, Љиљана С; Поробић, Славица Ј; Aхренкиел, С Пхиллип; Лазић, Весна М; Недељковић, Јован М; | |
dc.rights.holder | © 2019 Taylor & Francis Group, LLC | |
dc.citation.volume | 54 | |
dc.citation.issue | 9 | |
dc.citation.spage | 899 | |
dc.citation.epage | 905 | |
dc.identifier.wos | 000471406200001 | |
dc.identifier.doi | 10.1080/10934529.2019.1606575 | |
dc.citation.rank | M23 | |
dc.identifier.pmid | 31045468 | |
dc.description.other | Supporting information: Sorption of divalent heavy metal ions onto functionalized biogenic hydroxyapatite with caffeic acid and 3,4-dihydroxybenzoic acid. Taylor & Francis. Smičiklas, Ivana D.; Lazić, Vesna M.; Živković, Ljiljana S.; Porobić, Slavica J.; Ahrenkiel, S. Phillip; Nedeljković, Jovan [https://doi.org/10.6084/m9.figshare.8068580.v1] | |
dc.description.other | Accepted manuscript version (postprint) available at: [http://vinar.vin.bg.ac.rs/handle/123456789/8188] | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-85065388855 |
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