Sorption of divalent heavy metal ions onto functionalized biogenic hydroxyapatite with caffeic acid and 3,4-dihydroxybenzoic acid
Нема приказа
Аутори
Smičiklas, Ivana D.Lazić, Vesna M.
Živković, Ljiljana
Porobić, Slavica
Ahrenkiel, Scott Phillip
Nedeljković, Jovan
Чланак у часопису (Објављена верзија)
,
© 2019 Taylor & Francis Group, LLC
Метаподаци
Приказ свих података о документуАпстракт
The sorption ability of biogenic hydroxyapatite (BHAP) towards heavy metal ions (Pb, Cu, Ni, Cd, and Zn) is compared with functionalized BHAP powders with caffeic acid (CA) and 3,4-dihydroxybenzoic acid (3,4-DHBA). The functionalization of the BHAP with either CA or 3,4-DHBA is indicated by the appearance of the colored powders due to the formation of the interfacial charge transfer (ICT) complexes. The detailed characterization of as-prepared and functionalized BHAP samples was performed using transmission electron microscopy, reflection spectroscopy, thermogravimetric analysis and determination of zeta potential. All three sorbents clearly displayed preferential sorption of Pb ions when the total concentration of multi-component equimolar solutions of heavy metal ions is high. It should be emphasized that the sorption capacity of functionalized BHAP with either CA or 3,4-BHAP was found to be higher, up to 60%, compared to as-prepared BHAP without the decrease of selectivity towards P...b ions. © 2019, © 2019 Taylor & Francis Group, LLC.
Кључне речи:
Animal bones / hydroxyapatite / sorption / heavy metal ions / functionalization / catechol derivativesИзвор:
Journal of Environmental Science and Health, Part A, 2019, 54, 9, 899-905Финансирање / пројекти:
- Материјали редуковане димензионалности за ефикасну апсорпцију светлости и конверзију енергије (RS-45020)
- Нове технологије за мониторинг и заштиту животног окружења од штетних хемијских супстанци и радијационог оптерећења (RS-43009)
Напомена:
- Supporting information: Sorption of divalent heavy metal ions onto functionalized biogenic hydroxyapatite with caffeic acid and 3,4-dihydroxybenzoic acid. Taylor & Francis. Smičiklas, Ivana D.; Lazić, Vesna M.; Živković, Ljiljana S.; Porobić, Slavica J.; Ahrenkiel, S. Phillip; Nedeljković, Jovan https://doi.org/10.6084/m9.figshare.8068580.v1
- Accepted manuscript version (postprint) available at: http://vinar.vin.bg.ac.rs/handle/123456789/8188
DOI: 10.1080/10934529.2019.1606575
ISSN: 1093-4529
PubMed: 31045468
WoS: 000471406200001
Scopus: 2-s2.0-85065388855
Колекције
Институција/група
VinčaTY - JOUR AU - Smičiklas, Ivana D. AU - Lazić, Vesna M. AU - Živković, Ljiljana AU - Porobić, Slavica AU - Ahrenkiel, Scott Phillip AU - Nedeljković, Jovan PY - 2019 UR - https://vinar.vin.bg.ac.rs/handle/123456789/8172 AB - The sorption ability of biogenic hydroxyapatite (BHAP) towards heavy metal ions (Pb, Cu, Ni, Cd, and Zn) is compared with functionalized BHAP powders with caffeic acid (CA) and 3,4-dihydroxybenzoic acid (3,4-DHBA). The functionalization of the BHAP with either CA or 3,4-DHBA is indicated by the appearance of the colored powders due to the formation of the interfacial charge transfer (ICT) complexes. The detailed characterization of as-prepared and functionalized BHAP samples was performed using transmission electron microscopy, reflection spectroscopy, thermogravimetric analysis and determination of zeta potential. All three sorbents clearly displayed preferential sorption of Pb ions when the total concentration of multi-component equimolar solutions of heavy metal ions is high. It should be emphasized that the sorption capacity of functionalized BHAP with either CA or 3,4-BHAP was found to be higher, up to 60%, compared to as-prepared BHAP without the decrease of selectivity towards Pb ions. © 2019, © 2019 Taylor & Francis Group, LLC. T2 - Journal of Environmental Science and Health, Part A T1 - Sorption of divalent heavy metal ions onto functionalized biogenic hydroxyapatite with caffeic acid and 3,4-dihydroxybenzoic acid VL - 54 IS - 9 SP - 899 EP - 905 DO - 10.1080/10934529.2019.1606575 ER -
@article{ author = "Smičiklas, Ivana D. and Lazić, Vesna M. and Živković, Ljiljana and Porobić, Slavica and Ahrenkiel, Scott Phillip and Nedeljković, Jovan", year = "2019", abstract = "The sorption ability of biogenic hydroxyapatite (BHAP) towards heavy metal ions (Pb, Cu, Ni, Cd, and Zn) is compared with functionalized BHAP powders with caffeic acid (CA) and 3,4-dihydroxybenzoic acid (3,4-DHBA). The functionalization of the BHAP with either CA or 3,4-DHBA is indicated by the appearance of the colored powders due to the formation of the interfacial charge transfer (ICT) complexes. The detailed characterization of as-prepared and functionalized BHAP samples was performed using transmission electron microscopy, reflection spectroscopy, thermogravimetric analysis and determination of zeta potential. All three sorbents clearly displayed preferential sorption of Pb ions when the total concentration of multi-component equimolar solutions of heavy metal ions is high. It should be emphasized that the sorption capacity of functionalized BHAP with either CA or 3,4-BHAP was found to be higher, up to 60%, compared to as-prepared BHAP without the decrease of selectivity towards Pb ions. © 2019, © 2019 Taylor & Francis Group, LLC.", journal = "Journal of Environmental Science and Health, Part A", title = "Sorption of divalent heavy metal ions onto functionalized biogenic hydroxyapatite with caffeic acid and 3,4-dihydroxybenzoic acid", volume = "54", number = "9", pages = "899-905", doi = "10.1080/10934529.2019.1606575" }
Smičiklas, I. D., Lazić, V. M., Živković, L., Porobić, S., Ahrenkiel, S. P.,& Nedeljković, J.. (2019). Sorption of divalent heavy metal ions onto functionalized biogenic hydroxyapatite with caffeic acid and 3,4-dihydroxybenzoic acid. in Journal of Environmental Science and Health, Part A, 54(9), 899-905. https://doi.org/10.1080/10934529.2019.1606575
Smičiklas ID, Lazić VM, Živković L, Porobić S, Ahrenkiel SP, Nedeljković J. Sorption of divalent heavy metal ions onto functionalized biogenic hydroxyapatite with caffeic acid and 3,4-dihydroxybenzoic acid. in Journal of Environmental Science and Health, Part A. 2019;54(9):899-905. doi:10.1080/10934529.2019.1606575 .
Smičiklas, Ivana D., Lazić, Vesna M., Živković, Ljiljana, Porobić, Slavica, Ahrenkiel, Scott Phillip, Nedeljković, Jovan, "Sorption of divalent heavy metal ions onto functionalized biogenic hydroxyapatite with caffeic acid and 3,4-dihydroxybenzoic acid" in Journal of Environmental Science and Health, Part A, 54, no. 9 (2019):899-905, https://doi.org/10.1080/10934529.2019.1606575 . .