Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia
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2019
Authors
Ognjanović, MilošStanković, Dalibor M.
Ming, Yue
Zhang, Hongguo
Jančar, Boštjan
Dojčinović, Biljana P.
Prijović, Željko
Antić, Bratislav
Article (Published version)
,
© 2018 Elsevier B.V.
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In a new approach based on a two-step procedure, co-precipitation method followed by hydrothermal treatment in a microwave field, Zn-substituted Fe3O4 nanoparticles (ZnxFe3-xO4) were synthesized. Results of XRD, FT–IR and TEM analysis clearly demonstrate that nanoparticles were single phase, crystallizing in the spinel structure type (S.G. Fd3¯m) with crystallite size in the range of 2–20 nm, which strongly depends on Zn concentration. The produced nanoparticles were used for fabrication of modified carbon paste electrodes as a novel system for electrochemical non-enzymatic glucose detection. It was found that the increase of zinc concentration up to the value of x = 0.56 (Zn0.56Fe2.44O4) of as-prepared nanoparticles was followed with an increase of a performance of the modified carbon paste electrode toward glucose detection. Linear working range from 0.1 to 2 mM was obtained with detection limit of 0.03 mM, and with fast response time (<3 s). Proposed sensor was successfully applied ...for the determination of glucose level in real samples with satisfactory recovery. The synthesized zinc-ferrite samples were also tested as potential heating agents in magnetic hyperthermia. The heating ability (SAR value) increases with x value, reaching maximum for x = 0.37. This is correlated with changes of particle size and magnetic characteristics which strongly depend on Zn concentration. © 2018 Elsevier B.V.
Keywords:
MW hydrothermal synthesis / Structural characterization / Carbon electrodes / Glucose sensor / HyperthermiaSource:
Journal of Alloys and Compounds, 2019, 777, 454-462Funding / projects:
- Ministry of Education, Science and Technological Development of the Republic of Serbia through the Eureka Project (E!9982)
- Strengthening of the MagBioVin Research and Innovation Team for Development of Novel Approaches for Tumour Therapy based on Nanostructured Materials (EU-FP7-621375)
DOI: 10.1016/j.jallcom.2018.10.369
ISSN: 0925-8388
WoS: 000454856800055
Scopus: 2-s2.0-85056178941
URI
https://linkinghub.elsevier.com/retrieve/pii/S0925838818340684https://vinar.vin.bg.ac.rs/handle/123456789/7942
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VinčaTY - JOUR AU - Ognjanović, Miloš AU - Stanković, Dalibor M. AU - Ming, Yue AU - Zhang, Hongguo AU - Jančar, Boštjan AU - Dojčinović, Biljana P. AU - Prijović, Željko AU - Antić, Bratislav PY - 2019 UR - https://linkinghub.elsevier.com/retrieve/pii/S0925838818340684 UR - https://vinar.vin.bg.ac.rs/handle/123456789/7942 AB - In a new approach based on a two-step procedure, co-precipitation method followed by hydrothermal treatment in a microwave field, Zn-substituted Fe3O4 nanoparticles (ZnxFe3-xO4) were synthesized. Results of XRD, FT–IR and TEM analysis clearly demonstrate that nanoparticles were single phase, crystallizing in the spinel structure type (S.G. Fd3¯m) with crystallite size in the range of 2–20 nm, which strongly depends on Zn concentration. The produced nanoparticles were used for fabrication of modified carbon paste electrodes as a novel system for electrochemical non-enzymatic glucose detection. It was found that the increase of zinc concentration up to the value of x = 0.56 (Zn0.56Fe2.44O4) of as-prepared nanoparticles was followed with an increase of a performance of the modified carbon paste electrode toward glucose detection. Linear working range from 0.1 to 2 mM was obtained with detection limit of 0.03 mM, and with fast response time (<3 s). Proposed sensor was successfully applied for the determination of glucose level in real samples with satisfactory recovery. The synthesized zinc-ferrite samples were also tested as potential heating agents in magnetic hyperthermia. The heating ability (SAR value) increases with x value, reaching maximum for x = 0.37. This is correlated with changes of particle size and magnetic characteristics which strongly depend on Zn concentration. © 2018 Elsevier B.V. T2 - Journal of Alloys and Compounds T1 - Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia VL - 777 SP - 454 EP - 462 DO - 10.1016/j.jallcom.2018.10.369 ER -
@article{ author = "Ognjanović, Miloš and Stanković, Dalibor M. and Ming, Yue and Zhang, Hongguo and Jančar, Boštjan and Dojčinović, Biljana P. and Prijović, Željko and Antić, Bratislav", year = "2019", abstract = "In a new approach based on a two-step procedure, co-precipitation method followed by hydrothermal treatment in a microwave field, Zn-substituted Fe3O4 nanoparticles (ZnxFe3-xO4) were synthesized. Results of XRD, FT–IR and TEM analysis clearly demonstrate that nanoparticles were single phase, crystallizing in the spinel structure type (S.G. Fd3¯m) with crystallite size in the range of 2–20 nm, which strongly depends on Zn concentration. The produced nanoparticles were used for fabrication of modified carbon paste electrodes as a novel system for electrochemical non-enzymatic glucose detection. It was found that the increase of zinc concentration up to the value of x = 0.56 (Zn0.56Fe2.44O4) of as-prepared nanoparticles was followed with an increase of a performance of the modified carbon paste electrode toward glucose detection. Linear working range from 0.1 to 2 mM was obtained with detection limit of 0.03 mM, and with fast response time (<3 s). Proposed sensor was successfully applied for the determination of glucose level in real samples with satisfactory recovery. The synthesized zinc-ferrite samples were also tested as potential heating agents in magnetic hyperthermia. The heating ability (SAR value) increases with x value, reaching maximum for x = 0.37. This is correlated with changes of particle size and magnetic characteristics which strongly depend on Zn concentration. © 2018 Elsevier B.V.", journal = "Journal of Alloys and Compounds", title = "Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia", volume = "777", pages = "454-462", doi = "10.1016/j.jallcom.2018.10.369" }
Ognjanović, M., Stanković, D. M., Ming, Y., Zhang, H., Jančar, B., Dojčinović, B. P., Prijović, Ž.,& Antić, B.. (2019). Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia. in Journal of Alloys and Compounds, 777, 454-462. https://doi.org/10.1016/j.jallcom.2018.10.369
Ognjanović M, Stanković DM, Ming Y, Zhang H, Jančar B, Dojčinović BP, Prijović Ž, Antić B. Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia. in Journal of Alloys and Compounds. 2019;777:454-462. doi:10.1016/j.jallcom.2018.10.369 .
Ognjanović, Miloš, Stanković, Dalibor M., Ming, Yue, Zhang, Hongguo, Jančar, Boštjan, Dojčinović, Biljana P., Prijović, Željko, Antić, Bratislav, "Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia" in Journal of Alloys and Compounds, 777 (2019):454-462, https://doi.org/10.1016/j.jallcom.2018.10.369 . .