Electrochemical tuning of capacitive response of graphene oxide
AuthorsGutić, Sanjin J.
Kozlica, Dževad K.
Bajuk-Bogdanović, Danica V.
Mirsky, Vladimir M.
Mentus, Slavko V.
Pašti, Igor A.
Article (Accepted Version)
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The increasing energy demands of modern society require a deep understanding of the properties of energy storage materials, as well as the tuning of their performance. We show that the capacitance of graphene oxide (GO) can be precisely tuned using a simple electrochemical reduction route. In situ resistance measurements, in combination with cyclic voltammetry measurements and Raman spectroscopy, have shown that upon reduction GO is irreversibly deoxygenated, which is further accompanied by structural ordering and an increase in electrical conductivity. The capacitance is maximized when the concentration of oxygen functional groups is properly balanced with the conductivity. Any further reduction and deoxygenation leads to a gradual loss of capacitance. The observed trend is independent of the preparation route and the exact chemical and structural properties of GO. It is proposed that an improvement in the capacitive properties of any GO can be achieved by optimization of its reductio...n conditions.
Keywords:graphene / graphene oxide / capacitance / electrochemical reduction
Source:Physical Chemistry Chemical Physics, 2018, 20, 35, 22698-22709
- Lithium-ion batteries and fuel cells - research and development (RS-45014)
- Serbian Academy of Sciences and Arts ("Electrocatalysis in the contemporary processes of energy conversion")
- This is the peer-reviewed version of the following article: Gutić, Sanjin J., Dževad Kozlica, Fehim Korać, Danica Bajuk-Bogdanović, Miodrag Mitrić, Vladimir M. Mirsky, Slavko V. Mentus, and Igor A. Pašti. "Electrochemical tuning of capacitive response of graphene oxide." (2018). https://doi.org/10.1039/C8CP03631D