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dc.creatorRadoman, Tijana S.
dc.creatorDžunuzović, Jasna V.
dc.creatorSpasojević, Pavle M.
dc.creatorMarinović-Cincović, Milena
dc.creatorJeremić, Katarina B.
dc.creatorPopović, Ivanka G.
dc.creatorDžunuzović, Enis S.
dc.date.accessioned2018-08-02T12:13:08Z
dc.date.available2018-08-02T12:13:08Z
dc.date.issued2018
dc.identifier.issn0272-8397 (print)
dc.identifier.issn1548-0569 (electronic)
dc.identifier.urihttp://doi.wiley.com/10.1002/pc.24089
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/7789
dc.description.abstractAlkyd resin/TiO2 nanocomposites (NC) were prepared from short oil alkyd resin and TiO2 nanoparticles (NPs) surface modified with in situ formed imine ligand, based on 3,4-dihydroxybenzaldehyde and oleylamine, or with three gallic acid esters. The short oil alkyd resin was synthesized from sunflower oil, phthalic anhydride, and trimethylolpropane. Unmodified and surface modified TiO2 NPs were examined by transmission electron microscopy. Rheological investigation revealed that prepared dispersions have higher dynamic viscosity than pure alkyd resin. Using different characterization methods it was obtained that NCs have similar thermooxidative stability as alkyd resin, lower glass transition temperature, better barrier properties, enhanced hardness, better chemical resistance, and lower adhesion to the metal, except in the case of NC prepared using TiO2 NPs surface modified with imine, which exhibited better adhesion to the metal than pure alkyd resin.en
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172062/RS//
dc.rightsrestrictedAccess
dc.sourcePolymer Composites
dc.subjectadhesionen
dc.subjectchemical stabilityen
dc.subjectglass transitionen
dc.subjecthigh resolution transmission electron microscopyen
dc.subjectnanocompositesen
dc.subjectnanoparticlesen
dc.subjectresinsen
dc.subjectsunflower oilen
dc.subjecttitanium dioxideen
dc.subjecttransmission electron microscopyen
dc.titlePreparation and properties of short oil alkyd resin/TiO 2 nanocomposites based on surface modified TiO 2 nanoparticlesen
dc.typearticleen
dc.rights.licenseARR
dcterms.abstractДжунузовић, Енис С.; Поповић, Иванка Г.; Радоман, Тијана С; Джунузовић, Јасна В.; Спасојевић, Павле М.; Мариновић-Цинцовић, Милена Т.; Јеремић, Катарина Б.;
dc.rights.holder© 2016 Society of Plastics Engineers
dc.citation.volume39
dc.citation.issue5
dc.citation.spage1488
dc.citation.epage1499
dc.identifier.wos000436299100010
dc.identifier.doi10.1002/pc.24089
dc.type.versionpublishedVersion
dc.identifier.scopus2-s2.0-84973352568


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