The impact of the structure of graphene-based materials on the removal of organophosphorus pesticides from water
Само за регистроване кориснике
2018
Аутори
Lazarević-Pašti, TamaraAnićijević, Vladan J.
Baljozović, Miloš
Vasić Anićijević, Dragana D.
Gutić, Sanjin J.
Vasić, Vesna M.
Skorodumova, Natalia V.
Pašti, Igor A.
Чланак у часопису (Објављена верзија)
,
© 2018 The Royal Society of Chemistry
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The wide use of pesticides in modern agriculture and other areas results in an urgent need for their efficient removal from the environment. Adsorption of pesticides is one of the most commonly used strategies for this task. Here we analyze the adsorption of two organophosphorus pesticides, dimethoate (DMT) and chlorpyrifos (CPF), on graphene-based materials. The adsorption was found to be very sensitive to the structure of the adsorbents used. In particular, aliphatic DMT was found to prefer hydrophilic oxidized graphene surfaces. The CPF molecule, which contains an aromatic moiety, prefers adsorption on the surface of a graphene basal plane with high structural order and preserved π electron system. The toxicity of pesticide solutions is reduced after adsorption, suggesting that there is no oxidation of DMT and CPF to more toxic oxo forms. We emphasize that the combination of structural properties of adsorbents and adsorbates defines the adsorption of organophosphorus pesticides on g...raphene-based materials, while the specific surface area of adsorbents is not the major factor.
Извор:
Environmental Science: Nano, 2018, 5, 6, 1482-1494Финансирање / пројекти:
- Истраживања интеракција ензима са токсичним и фармаколошки активним молекулима (RS-MESTD-Basic Research (BR or ON)-172023)
- Swedish Research Council (2014-5993)
- Carl Tryggers Foundation for Scientific Research
- Swiss National Science Foundation (200020-153549)
- Swiss National Science Foundation (200020-175800)
- Swiss National Science Foundation (206021-113149)
DOI: 10.1039/C8EN00171E
ISSN: 2051-8153; 2051-8161
WoS: 000435355700016
Scopus: 2-s2.0-85048794880
Колекције
Институција/група
VinčaTY - JOUR AU - Lazarević-Pašti, Tamara AU - Anićijević, Vladan J. AU - Baljozović, Miloš AU - Vasić Anićijević, Dragana D. AU - Gutić, Sanjin J. AU - Vasić, Vesna M. AU - Skorodumova, Natalia V. AU - Pašti, Igor A. PY - 2018 UR - http://xlink.rsc.org/?DOI=C8EN00171E UR - https://vinar.vin.bg.ac.rs/handle/123456789/7730 AB - The wide use of pesticides in modern agriculture and other areas results in an urgent need for their efficient removal from the environment. Adsorption of pesticides is one of the most commonly used strategies for this task. Here we analyze the adsorption of two organophosphorus pesticides, dimethoate (DMT) and chlorpyrifos (CPF), on graphene-based materials. The adsorption was found to be very sensitive to the structure of the adsorbents used. In particular, aliphatic DMT was found to prefer hydrophilic oxidized graphene surfaces. The CPF molecule, which contains an aromatic moiety, prefers adsorption on the surface of a graphene basal plane with high structural order and preserved π electron system. The toxicity of pesticide solutions is reduced after adsorption, suggesting that there is no oxidation of DMT and CPF to more toxic oxo forms. We emphasize that the combination of structural properties of adsorbents and adsorbates defines the adsorption of organophosphorus pesticides on graphene-based materials, while the specific surface area of adsorbents is not the major factor. T2 - Environmental Science: Nano T1 - The impact of the structure of graphene-based materials on the removal of organophosphorus pesticides from water VL - 5 IS - 6 SP - 1482 EP - 1494 DO - 10.1039/C8EN00171E ER -
@article{ author = "Lazarević-Pašti, Tamara and Anićijević, Vladan J. and Baljozović, Miloš and Vasić Anićijević, Dragana D. and Gutić, Sanjin J. and Vasić, Vesna M. and Skorodumova, Natalia V. and Pašti, Igor A.", year = "2018", abstract = "The wide use of pesticides in modern agriculture and other areas results in an urgent need for their efficient removal from the environment. Adsorption of pesticides is one of the most commonly used strategies for this task. Here we analyze the adsorption of two organophosphorus pesticides, dimethoate (DMT) and chlorpyrifos (CPF), on graphene-based materials. The adsorption was found to be very sensitive to the structure of the adsorbents used. In particular, aliphatic DMT was found to prefer hydrophilic oxidized graphene surfaces. The CPF molecule, which contains an aromatic moiety, prefers adsorption on the surface of a graphene basal plane with high structural order and preserved π electron system. The toxicity of pesticide solutions is reduced after adsorption, suggesting that there is no oxidation of DMT and CPF to more toxic oxo forms. We emphasize that the combination of structural properties of adsorbents and adsorbates defines the adsorption of organophosphorus pesticides on graphene-based materials, while the specific surface area of adsorbents is not the major factor.", journal = "Environmental Science: Nano", title = "The impact of the structure of graphene-based materials on the removal of organophosphorus pesticides from water", volume = "5", number = "6", pages = "1482-1494", doi = "10.1039/C8EN00171E" }
Lazarević-Pašti, T., Anićijević, V. J., Baljozović, M., Vasić Anićijević, D. D., Gutić, S. J., Vasić, V. M., Skorodumova, N. V.,& Pašti, I. A.. (2018). The impact of the structure of graphene-based materials on the removal of organophosphorus pesticides from water. in Environmental Science: Nano, 5(6), 1482-1494. https://doi.org/10.1039/C8EN00171E
Lazarević-Pašti T, Anićijević VJ, Baljozović M, Vasić Anićijević DD, Gutić SJ, Vasić VM, Skorodumova NV, Pašti IA. The impact of the structure of graphene-based materials on the removal of organophosphorus pesticides from water. in Environmental Science: Nano. 2018;5(6):1482-1494. doi:10.1039/C8EN00171E .
Lazarević-Pašti, Tamara, Anićijević, Vladan J., Baljozović, Miloš, Vasić Anićijević, Dragana D., Gutić, Sanjin J., Vasić, Vesna M., Skorodumova, Natalia V., Pašti, Igor A., "The impact of the structure of graphene-based materials on the removal of organophosphorus pesticides from water" in Environmental Science: Nano, 5, no. 6 (2018):1482-1494, https://doi.org/10.1039/C8EN00171E . .