Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction
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2018
Authors
Zdolšek, NikolaDimitrijević, Aleksandra
Bendova, Magdalena
Krstić, Jugoslav B.
Rocha, Raquel P.
Figueiredo, Jose L.
Bajuk-Bogdanović, Danica V.
Trtić-Petrović, Tatjana M.
Šljukić, Biljana
Article (Published version)
,
© 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
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Carbon materials, prepared by using different methods with ionicliquids, are compared as electrocatalysts for the oxygen reductionreaction (ORR). Materials were synthesized through the hydrothermalcarbonization of glucose and by using the same method in the presence of1-butyl-3-methylimidazolium methanesulfonate {[}bmim]{[}MeSO3] as anadditive. Another two carbon-based materials were prepared by usingionic-liquid-based methods: ionothermal carbonization of glucose using{[}bmim]{[}MeSO3] as a recyclable medium for the carbonization reactionand by direct carbonization of the ionic liquid in a one-step methodusing {[}bmim]{[}MeSO3] as the precursor for N- and S-doped porouscarbon (Carb-IL). Characterization results showed the possibility ofmorphology and porosity control by using {[}bmim]{[}MeSO3]. Allmaterials were subsequently tested for the ORR in alkaline media.Carb-IL showed enhanced and stable electrocatalytic ORR activity, evenin the presence of methanol, ethanol, and borohydride, ...opening thepossibility for its application in fuel cells.
Keywords:
ionic liquids / porous carbon materials / fuel cells / ionothermal carbonization / oxygen reduction reactionSource:
ChemElectroChem, 2018, 5, 7, 1037-1046Funding / projects:
- Physics and Chemistry with Ion Beams (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45006)
- Lithium-ion batteries and fuel cells - research and development (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45014)
- Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
- ERDF through COMPETE - Programa Operacional Competitividade e Internacionalizacao (POCI) [POCI-01-0145-FEDER-006984]
- FCT - Fundacao para a Ciencia e a Tecnologia [SFRH/BD/95411/2013]
- Ministry of Education, Sports, and Youth of the Czech Republic [COST LD14090]
- COST Action [CM1206]
Note:
- Peer-reviewed article: https://vinar.vin.bg.ac.rs/handle/123456789/9881
Related info:
- Referenced by
https://vinar.vin.bg.ac.rs/handle/123456789/9881
DOI: 10.1002/celc.201701369
ISSN: 2196-0216
WoS: 000429413700007
Scopus: 2-s2.0-85041637185
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VinčaTY - JOUR AU - Zdolšek, Nikola AU - Dimitrijević, Aleksandra AU - Bendova, Magdalena AU - Krstić, Jugoslav B. AU - Rocha, Raquel P. AU - Figueiredo, Jose L. AU - Bajuk-Bogdanović, Danica V. AU - Trtić-Petrović, Tatjana M. AU - Šljukić, Biljana PY - 2018 UR - https://vinar.vin.bg.ac.rs/handle/123456789/7672 AB - Carbon materials, prepared by using different methods with ionicliquids, are compared as electrocatalysts for the oxygen reductionreaction (ORR). Materials were synthesized through the hydrothermalcarbonization of glucose and by using the same method in the presence of1-butyl-3-methylimidazolium methanesulfonate {[}bmim]{[}MeSO3] as anadditive. Another two carbon-based materials were prepared by usingionic-liquid-based methods: ionothermal carbonization of glucose using{[}bmim]{[}MeSO3] as a recyclable medium for the carbonization reactionand by direct carbonization of the ionic liquid in a one-step methodusing {[}bmim]{[}MeSO3] as the precursor for N- and S-doped porouscarbon (Carb-IL). Characterization results showed the possibility ofmorphology and porosity control by using {[}bmim]{[}MeSO3]. Allmaterials were subsequently tested for the ORR in alkaline media.Carb-IL showed enhanced and stable electrocatalytic ORR activity, evenin the presence of methanol, ethanol, and borohydride, opening thepossibility for its application in fuel cells. T2 - ChemElectroChem T1 - Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction VL - 5 IS - 7 SP - 1037 EP - 1046 DO - 10.1002/celc.201701369 ER -
@article{ author = "Zdolšek, Nikola and Dimitrijević, Aleksandra and Bendova, Magdalena and Krstić, Jugoslav B. and Rocha, Raquel P. and Figueiredo, Jose L. and Bajuk-Bogdanović, Danica V. and Trtić-Petrović, Tatjana M. and Šljukić, Biljana", year = "2018", abstract = "Carbon materials, prepared by using different methods with ionicliquids, are compared as electrocatalysts for the oxygen reductionreaction (ORR). Materials were synthesized through the hydrothermalcarbonization of glucose and by using the same method in the presence of1-butyl-3-methylimidazolium methanesulfonate {[}bmim]{[}MeSO3] as anadditive. Another two carbon-based materials were prepared by usingionic-liquid-based methods: ionothermal carbonization of glucose using{[}bmim]{[}MeSO3] as a recyclable medium for the carbonization reactionand by direct carbonization of the ionic liquid in a one-step methodusing {[}bmim]{[}MeSO3] as the precursor for N- and S-doped porouscarbon (Carb-IL). Characterization results showed the possibility ofmorphology and porosity control by using {[}bmim]{[}MeSO3]. Allmaterials were subsequently tested for the ORR in alkaline media.Carb-IL showed enhanced and stable electrocatalytic ORR activity, evenin the presence of methanol, ethanol, and borohydride, opening thepossibility for its application in fuel cells.", journal = "ChemElectroChem", title = "Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction", volume = "5", number = "7", pages = "1037-1046", doi = "10.1002/celc.201701369" }
Zdolšek, N., Dimitrijević, A., Bendova, M., Krstić, J. B., Rocha, R. P., Figueiredo, J. L., Bajuk-Bogdanović, D. V., Trtić-Petrović, T. M.,& Šljukić, B.. (2018). Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction. in ChemElectroChem, 5(7), 1037-1046. https://doi.org/10.1002/celc.201701369
Zdolšek N, Dimitrijević A, Bendova M, Krstić JB, Rocha RP, Figueiredo JL, Bajuk-Bogdanović DV, Trtić-Petrović TM, Šljukić B. Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction. in ChemElectroChem. 2018;5(7):1037-1046. doi:10.1002/celc.201701369 .
Zdolšek, Nikola, Dimitrijević, Aleksandra, Bendova, Magdalena, Krstić, Jugoslav B., Rocha, Raquel P., Figueiredo, Jose L., Bajuk-Bogdanović, Danica V., Trtić-Petrović, Tatjana M., Šljukić, Biljana, "Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction" in ChemElectroChem, 5, no. 7 (2018):1037-1046, https://doi.org/10.1002/celc.201701369 . .