Herbicide clomazone detection using electroanalytical approach using boron doped diamond electrode
Аутори
Đurđić, SlađanaVukojević, Vesna
Jevtić, Sonja
Pergal, Marija V.
Petković, Branka B.
Stanković, Dalibor M.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
In this work, for the first time we proposed electrochemical behavior and development of an analytical procedure for quantification of pesticide clomazone. Electrochemical behavior of clomazone's at boron-doped diamond electrode is characterized with irreversible oxidation at potential of around 1.6 V, in Britton-Robinson buffer solution at pH 2. It was found that potential of this oxidation was not pH dependent excluding presence of proton in the electrochemical reaction. Square wave voltammetry method was the most appropriate for clomazone quantification and proposed procedure was successfully applied for determination of clomazone in river water samples. Obtained parameters, detection limit of 0.21 mu M and working linear range from 1 to 100 mu M and satisfied selectivity can indicate that presented results open new field in research of this group of pesticides and offer possible replacement to the sophisticated and expensive chromatographic methods.
Кључне речи:
boron doped diamond electrode / clomazone / electrochemistryИзвор:
International Journal of Electrochemical Science, 2018, 13, 3, 2791-2799Финансирање / пројекти:
- Примена унапређених оксидационих процеса и наноструктурисаних оксидних материјала за уклањање загађивача из животне средине, развој и оптимизација инструменталних техника за праћење ефикасности (RS-MESTD-Basic Research (BR or ON)-172030)
- Вишескално структурирање полимерних нанокомпозита и функционалних материјала применом различитих прекурсора (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45022)
- Strengthening of the MagBioVin Research and Innovation Team for Development of Novel Approaches for Tumour Therapy based on Nanostructured Materials (EU-FP7-621375)
DOI: 10.20964/2018.03.39
ISSN: 1452-3981
WoS: 000429101700049
Scopus: 2-s2.0-85042787052
Колекције
Институција/група
VinčaTY - JOUR AU - Đurđić, Slađana AU - Vukojević, Vesna AU - Jevtić, Sonja AU - Pergal, Marija V. AU - Petković, Branka B. AU - Stanković, Dalibor M. PY - 2018 UR - https://vinar.vin.bg.ac.rs/handle/123456789/7661 AB - In this work, for the first time we proposed electrochemical behavior and development of an analytical procedure for quantification of pesticide clomazone. Electrochemical behavior of clomazone's at boron-doped diamond electrode is characterized with irreversible oxidation at potential of around 1.6 V, in Britton-Robinson buffer solution at pH 2. It was found that potential of this oxidation was not pH dependent excluding presence of proton in the electrochemical reaction. Square wave voltammetry method was the most appropriate for clomazone quantification and proposed procedure was successfully applied for determination of clomazone in river water samples. Obtained parameters, detection limit of 0.21 mu M and working linear range from 1 to 100 mu M and satisfied selectivity can indicate that presented results open new field in research of this group of pesticides and offer possible replacement to the sophisticated and expensive chromatographic methods. T2 - International Journal of Electrochemical Science T1 - Herbicide clomazone detection using electroanalytical approach using boron doped diamond electrode VL - 13 IS - 3 SP - 2791 EP - 2799 DO - 10.20964/2018.03.39 ER -
@article{ author = "Đurđić, Slađana and Vukojević, Vesna and Jevtić, Sonja and Pergal, Marija V. and Petković, Branka B. and Stanković, Dalibor M.", year = "2018", abstract = "In this work, for the first time we proposed electrochemical behavior and development of an analytical procedure for quantification of pesticide clomazone. Electrochemical behavior of clomazone's at boron-doped diamond electrode is characterized with irreversible oxidation at potential of around 1.6 V, in Britton-Robinson buffer solution at pH 2. It was found that potential of this oxidation was not pH dependent excluding presence of proton in the electrochemical reaction. Square wave voltammetry method was the most appropriate for clomazone quantification and proposed procedure was successfully applied for determination of clomazone in river water samples. Obtained parameters, detection limit of 0.21 mu M and working linear range from 1 to 100 mu M and satisfied selectivity can indicate that presented results open new field in research of this group of pesticides and offer possible replacement to the sophisticated and expensive chromatographic methods.", journal = "International Journal of Electrochemical Science", title = "Herbicide clomazone detection using electroanalytical approach using boron doped diamond electrode", volume = "13", number = "3", pages = "2791-2799", doi = "10.20964/2018.03.39" }
Đurđić, S., Vukojević, V., Jevtić, S., Pergal, M. V., Petković, B. B.,& Stanković, D. M.. (2018). Herbicide clomazone detection using electroanalytical approach using boron doped diamond electrode. in International Journal of Electrochemical Science, 13(3), 2791-2799. https://doi.org/10.20964/2018.03.39
Đurđić S, Vukojević V, Jevtić S, Pergal MV, Petković BB, Stanković DM. Herbicide clomazone detection using electroanalytical approach using boron doped diamond electrode. in International Journal of Electrochemical Science. 2018;13(3):2791-2799. doi:10.20964/2018.03.39 .
Đurđić, Slađana, Vukojević, Vesna, Jevtić, Sonja, Pergal, Marija V., Petković, Branka B., Stanković, Dalibor M., "Herbicide clomazone detection using electroanalytical approach using boron doped diamond electrode" in International Journal of Electrochemical Science, 13, no. 3 (2018):2791-2799, https://doi.org/10.20964/2018.03.39 . .