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dc.creatorLaušević, Petar
dc.creatorPejović, Predrag
dc.creatorŽugić, Dragana
dc.creatorKochnev, Yuri
dc.creatorApel, Pavel
dc.creatorLaušević, Zoran
dc.date.accessioned2018-05-21T09:04:39Z
dc.date.available2018-05-21T09:04:39Z
dc.date.issued2018
dc.identifier.issn0957-4522 (print)
dc.identifier.urihttp://link.springer.com/10.1007/s10854-018-8740-x
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/7620
dc.description.abstractA novel self-supporting carbon thin film flexible supercapacitor electrode with high volumetric and areal capacitance was developed. The increase in capacitance performance is achieved by introducing channels across the carbon thin film using ion-track technology. In the first step of the electrode synthesis, latent tracks are inscribed in the starting polyimide (Kapton) foil by irradiation with 253 MeV Kr ions. Next, macropores in the form of cylindrical channels are formed by selective chemical etching with NaOCl along the ion tracks, creating ion-track polymer. With subsequent carbonization and activation of the ion-track polymer, activated ion-track carbon is produced. A range of samples are obtained by varying the chemical etching time of the irradiated polymer. In addition to channel formation the chemical etching time influences the composition of surface functional groups. The best results are obtained by chemical etching for 40 min, the thickness of the sample is 21 A mu m with channel density 2.4 x 10(6) cm(-2) and average channel diameter 430 nm. Beside cylindrical macro channels this material is mainly microporous with 0.62 nm pore diameter and shows the highest areal (494 mF/cm(2)), volumetric (224 F/cm(3)) and gravimetric (178 F/g) capacitance. As a consequence of channel formation, the rate capability of the supercapacitor was also increased.
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45006/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172045/RS//
dc.relationJoint Institute for Nuclear Research (JINR), Dubna, Russian Federation
dc.rightsrestrictedAccess
dc.sourceJournal of Materials Science: Materials in Electronics
dc.subjectvolumetric performance supercapacitorsen
dc.subjectporous carbonen
dc.subjectelectrochemical capacitorsen
dc.subjectenergy-storageen
dc.subjectgraphene oxideen
dc.subjectdoped carbonen
dc.subjectnitrogenen
dc.subjectpolyimideen
dc.subjectcompositesen
dc.titleImproving thin film flexible supercapacitor electrode properties using ion-track technology
dc.typearticleen
dc.rights.licenseARR
dcterms.abstractЖугић, Драгана; Aпел, Павел; Коцхнев, Yури; Пејовић, Предраг; Лаушевић, Зоран; Лаушевић, Петар;
dc.citation.volume29
dc.citation.issue9
dc.citation.spage7489
dc.citation.epage7500
dc.identifier.wos000429798300050
dc.identifier.doi10.1007/s10854-018-8740-x
dc.identifier.scopus2-s2.0-85041906918


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