Fluorine Doping of Layered NaxCoO2 Structure
Аутори
Jugović, DraganaMilović, Miloš
Mitrić, Miodrag
Cvjetićanin, Nikola
Avdeev, Max
Jokić, Bojan M.
Uskoković, Dragan
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The room temperature Na-ion secondary battery has been under focus lately due to its feasibility to compete against the already well-established Li-ion secondary battery. Transition metal oxides of general formula NaxMO2 have been investigated as potential cathode materials for sodium batteries. Layered NaxCoO2 is synthesized via solid-state method at 900 ºC in air atmosphere. Fluorine doping of the as-prepared powder is established by the use of ammonium hydrogen difluoride (NH4HF2) as a fluorinating agent. The fluorination takes place only at low temperature (200 ºC), while the treatment at higher temperatures (≥ 400 ºC) facilitates the formation of NaF. It is shown that various and controllable amounts of fluorine can be successfully incorporated into the structure. Finally, the effects of fluorine doping on both structural and electrochemical properties are examined.
Кључне речи:
Na-ion secondary batteries / fluorine / doping / NaxCoO2Извор:
YUCOMAT 2015 : 17th Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts, 2015, 12-12Издавач:
- Belgrade : Materials Research Society of Serbia
Финансирање / пројекти:
- Молекуларно дизајнирање наночестица контролисаних морфолошких и физичко-хемијских карактеристика и функционалних материјала на њиховој основи (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45004)
Напомена:
- YUCOMAT 2015 : 17th Annual Conference; August 31– September 4, Herceg Novi, 2015
Колекције
Институција/група
VinčaTY - CONF AU - Jugović, Dragana AU - Milović, Miloš AU - Mitrić, Miodrag AU - Cvjetićanin, Nikola AU - Avdeev, Max AU - Jokić, Bojan M. AU - Uskoković, Dragan PY - 2015 UR - https://vinar.vin.bg.ac.rs/handle/123456789/7543 AB - The room temperature Na-ion secondary battery has been under focus lately due to its feasibility to compete against the already well-established Li-ion secondary battery. Transition metal oxides of general formula NaxMO2 have been investigated as potential cathode materials for sodium batteries. Layered NaxCoO2 is synthesized via solid-state method at 900 ºC in air atmosphere. Fluorine doping of the as-prepared powder is established by the use of ammonium hydrogen difluoride (NH4HF2) as a fluorinating agent. The fluorination takes place only at low temperature (200 ºC), while the treatment at higher temperatures (≥ 400 ºC) facilitates the formation of NaF. It is shown that various and controllable amounts of fluorine can be successfully incorporated into the structure. Finally, the effects of fluorine doping on both structural and electrochemical properties are examined. PB - Belgrade : Materials Research Society of Serbia C3 - YUCOMAT 2015 : 17th Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts T1 - Fluorine Doping of Layered NaxCoO2 Structure SP - 12 EP - 12 UR - https://hdl.handle.net/21.15107/rcub_vinar_7543 ER -
@conference{ author = "Jugović, Dragana and Milović, Miloš and Mitrić, Miodrag and Cvjetićanin, Nikola and Avdeev, Max and Jokić, Bojan M. and Uskoković, Dragan", year = "2015", abstract = "The room temperature Na-ion secondary battery has been under focus lately due to its feasibility to compete against the already well-established Li-ion secondary battery. Transition metal oxides of general formula NaxMO2 have been investigated as potential cathode materials for sodium batteries. Layered NaxCoO2 is synthesized via solid-state method at 900 ºC in air atmosphere. Fluorine doping of the as-prepared powder is established by the use of ammonium hydrogen difluoride (NH4HF2) as a fluorinating agent. The fluorination takes place only at low temperature (200 ºC), while the treatment at higher temperatures (≥ 400 ºC) facilitates the formation of NaF. It is shown that various and controllable amounts of fluorine can be successfully incorporated into the structure. Finally, the effects of fluorine doping on both structural and electrochemical properties are examined.", publisher = "Belgrade : Materials Research Society of Serbia", journal = "YUCOMAT 2015 : 17th Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts", title = "Fluorine Doping of Layered NaxCoO2 Structure", pages = "12-12", url = "https://hdl.handle.net/21.15107/rcub_vinar_7543" }
Jugović, D., Milović, M., Mitrić, M., Cvjetićanin, N., Avdeev, M., Jokić, B. M.,& Uskoković, D.. (2015). Fluorine Doping of Layered NaxCoO2 Structure. in YUCOMAT 2015 : 17th Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts Belgrade : Materials Research Society of Serbia., 12-12. https://hdl.handle.net/21.15107/rcub_vinar_7543
Jugović D, Milović M, Mitrić M, Cvjetićanin N, Avdeev M, Jokić BM, Uskoković D. Fluorine Doping of Layered NaxCoO2 Structure. in YUCOMAT 2015 : 17th Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts. 2015;:12-12. https://hdl.handle.net/21.15107/rcub_vinar_7543 .
Jugović, Dragana, Milović, Miloš, Mitrić, Miodrag, Cvjetićanin, Nikola, Avdeev, Max, Jokić, Bojan M., Uskoković, Dragan, "Fluorine Doping of Layered NaxCoO2 Structure" in YUCOMAT 2015 : 17th Annual Conference YUCOMAT 2015 : Programme and The Book of Abstracts (2015):12-12, https://hdl.handle.net/21.15107/rcub_vinar_7543 .