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Europium(III)-doped A(2)Hf(2)O(7) (A = Y, Gd, Lu) nanoparticles: Influence of annealing temperature, europium(III) concentration and host cation on the luminescent properties
dc.creator | Papan, Jelena | |
dc.creator | Jovanović, Dragana J. | |
dc.creator | Vuković, Katarina | |
dc.creator | Smits, Krisjanis | |
dc.creator | Đorđević, Vesna R. | |
dc.creator | Dramićanin, Miroslav | |
dc.date.accessioned | 2018-03-03T15:03:32Z | |
dc.date.available | 2018-03-03T15:03:32Z | |
dc.date.issued | 2016 | |
dc.identifier.issn | 0925-3467 | |
dc.identifier.issn | 1873-1252 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/7132 | |
dc.description.abstract | The detailed analyses of structure and luminescence of europium(III)-doped A(2)Hf(2)O(7) (A = Y, Gd, Lu) nanoparticles is presented. Samples were prepared by time and cost effective combustion method that utilize polyethylene glycol both as a chelating agent and as a fuel, with different europium(III) concentrations (from 1 to 12 at.%), annealed at temperatures ranging from 800 to 1400 degrees C, and with alternating A(3+) cation in the A(2)Hf(2)O(7) host. Then, structural variations between materials were analysed by Xray diffraction and structural refinement, while the changes in the luminescence were assessed from the Judd-Ofelt analyses of emission spectra. Nanoparticles prepared at the lowest temperature (800 degrees C) had the smallest particle size of similar to 6 nm and showed the highest quantum efficiency when doped with 1 and 2 at.% of europium(III). Radiative transition rate and quantum efficiency of emission showed Lu2Hf2O7 GT Gd2Hf2O7 GT Y2Hf2O7 trend. (C) 2016 Elsevier B.V. All rights reserved. | en |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45020/RS// | |
dc.rights | restrictedAccess | en |
dc.source | Optical Materials | en |
dc.subject | Rare earth hafnate | en |
dc.subject | Phosphor | en |
dc.subject | Luminescence | en |
dc.subject | Judd-Ofelt | en |
dc.subject | Europium(III) | en |
dc.title | Europium(III)-doped A(2)Hf(2)O(7) (A = Y, Gd, Lu) nanoparticles: Influence of annealing temperature, europium(III) concentration and host cation on the luminescent properties | en |
dc.type | article | en |
dcterms.abstract | Јовановић Драгана; Смитс, Крисјанис; Вуковиц, Катарина; Ђорђевић Весна; Драмићанин Мирослав; Папан Јелена; | |
dc.citation.volume | 61 | |
dc.citation.spage | 68 | |
dc.citation.epage | 76 | |
dc.identifier.wos | 000388057500013 | |
dc.identifier.doi | 10.1016/j.optmat.2016.04.007 | |
dc.citation.other | Special Issue: SI | |
dc.citation.rank | M22 | |
dc.description.other | 4th International Conference on the Physics of Optical Materials and CI Devices (ICOM), Aug 31-Sep 04, 2015, Budva, Montenegro | en |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-84969143032 |