Structural Analysis of Single Wall Carbon Nanotubes Exposed to Oxidation and Reduction Conditions in the Course of Gamma Irradiation
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Jovanović, Svetlana P.Marković, Zoran M.
Kleut, Duška
Dramićanin, Miroslav
Holclajtner-Antunović, Ivanka D.
Milosavljević, Momir
La Parola, Valeria
Syrgiannis, Zois
Todorović-Marković, Biljana
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Single wall carbon nanotubes (SWCNTs) were exposed to gamma irradiation in oxidative (H2O, NH4OH) and reductive (H2O and NH4OH both mixed with isopropyl alcohol) media. The structure has been investigated with microscopic (atomic force and transmission electron microscopy), spectroscopic (Raman, X-ray photoelectron, and FTIR spectroscopy) techniques, and by thermogravimetric analysis. Reductive media offer the possibility for green chemistry reduction of SWCNTs: after gamma irradiation, SWCNTs lose C-O bonds. Furthermore, irradiation in these media increases the fraction of sp(2) hybridized carbon atoms in structure of SWCNTs and prevents their amorphization. The presence of isopropyl alcohol in reductive media contributed to the preservation of structures unity. On the other hand, the most effective procedure is the one that occurs in oxidative media and yields in debundled, cut, and annihilated carbon nanotubes. The smaller diameter and the metallic ones are the most affected.
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Journal of Physical Chemistry. C, 2014, 118, 29, 16147-16155Funding / projects:
- Thin films of single wall carbon nanotubes and graphene for electronic application (RS-MESTD-Basic Research (BR or ON)-172003)
DOI: 10.1021/jp502685n
ISSN: 1932-7447
WoS: 000339540700067
Scopus: 2-s2.0-84905041409
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VinčaTY - JOUR AU - Jovanović, Svetlana P. AU - Marković, Zoran M. AU - Kleut, Duška AU - Dramićanin, Miroslav AU - Holclajtner-Antunović, Ivanka D. AU - Milosavljević, Momir AU - La Parola, Valeria AU - Syrgiannis, Zois AU - Todorović-Marković, Biljana PY - 2014 UR - https://vinar.vin.bg.ac.rs/handle/123456789/6085 AB - Single wall carbon nanotubes (SWCNTs) were exposed to gamma irradiation in oxidative (H2O, NH4OH) and reductive (H2O and NH4OH both mixed with isopropyl alcohol) media. The structure has been investigated with microscopic (atomic force and transmission electron microscopy), spectroscopic (Raman, X-ray photoelectron, and FTIR spectroscopy) techniques, and by thermogravimetric analysis. Reductive media offer the possibility for green chemistry reduction of SWCNTs: after gamma irradiation, SWCNTs lose C-O bonds. Furthermore, irradiation in these media increases the fraction of sp(2) hybridized carbon atoms in structure of SWCNTs and prevents their amorphization. The presence of isopropyl alcohol in reductive media contributed to the preservation of structures unity. On the other hand, the most effective procedure is the one that occurs in oxidative media and yields in debundled, cut, and annihilated carbon nanotubes. The smaller diameter and the metallic ones are the most affected. T2 - Journal of Physical Chemistry. C T1 - Structural Analysis of Single Wall Carbon Nanotubes Exposed to Oxidation and Reduction Conditions in the Course of Gamma Irradiation VL - 118 IS - 29 SP - 16147 EP - 16155 DO - 10.1021/jp502685n ER -
@article{ author = "Jovanović, Svetlana P. and Marković, Zoran M. and Kleut, Duška and Dramićanin, Miroslav and Holclajtner-Antunović, Ivanka D. and Milosavljević, Momir and La Parola, Valeria and Syrgiannis, Zois and Todorović-Marković, Biljana", year = "2014", abstract = "Single wall carbon nanotubes (SWCNTs) were exposed to gamma irradiation in oxidative (H2O, NH4OH) and reductive (H2O and NH4OH both mixed with isopropyl alcohol) media. The structure has been investigated with microscopic (atomic force and transmission electron microscopy), spectroscopic (Raman, X-ray photoelectron, and FTIR spectroscopy) techniques, and by thermogravimetric analysis. Reductive media offer the possibility for green chemistry reduction of SWCNTs: after gamma irradiation, SWCNTs lose C-O bonds. Furthermore, irradiation in these media increases the fraction of sp(2) hybridized carbon atoms in structure of SWCNTs and prevents their amorphization. The presence of isopropyl alcohol in reductive media contributed to the preservation of structures unity. On the other hand, the most effective procedure is the one that occurs in oxidative media and yields in debundled, cut, and annihilated carbon nanotubes. The smaller diameter and the metallic ones are the most affected.", journal = "Journal of Physical Chemistry. C", title = "Structural Analysis of Single Wall Carbon Nanotubes Exposed to Oxidation and Reduction Conditions in the Course of Gamma Irradiation", volume = "118", number = "29", pages = "16147-16155", doi = "10.1021/jp502685n" }
Jovanović, S. P., Marković, Z. M., Kleut, D., Dramićanin, M., Holclajtner-Antunović, I. D., Milosavljević, M., La Parola, V., Syrgiannis, Z.,& Todorović-Marković, B.. (2014). Structural Analysis of Single Wall Carbon Nanotubes Exposed to Oxidation and Reduction Conditions in the Course of Gamma Irradiation. in Journal of Physical Chemistry. C, 118(29), 16147-16155. https://doi.org/10.1021/jp502685n
Jovanović SP, Marković ZM, Kleut D, Dramićanin M, Holclajtner-Antunović ID, Milosavljević M, La Parola V, Syrgiannis Z, Todorović-Marković B. Structural Analysis of Single Wall Carbon Nanotubes Exposed to Oxidation and Reduction Conditions in the Course of Gamma Irradiation. in Journal of Physical Chemistry. C. 2014;118(29):16147-16155. doi:10.1021/jp502685n .
Jovanović, Svetlana P., Marković, Zoran M., Kleut, Duška, Dramićanin, Miroslav, Holclajtner-Antunović, Ivanka D., Milosavljević, Momir, La Parola, Valeria, Syrgiannis, Zois, Todorović-Marković, Biljana, "Structural Analysis of Single Wall Carbon Nanotubes Exposed to Oxidation and Reduction Conditions in the Course of Gamma Irradiation" in Journal of Physical Chemistry. C, 118, no. 29 (2014):16147-16155, https://doi.org/10.1021/jp502685n . .