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Electrochemical oxidation of methanol on Pt/(RuxSn1-x)O-2 nanocatalyst
dc.creator | Krstajic, Mila N. | |
dc.creator | Obradović, Maja D. | |
dc.creator | Babić, Biljana M. | |
dc.creator | Radmilović, Velimir | |
dc.creator | Lacnjevac, Uros C. | |
dc.creator | Krstajic, Nedeljko V. | |
dc.creator | Gojković, Snežana Lj. | |
dc.date.accessioned | 2018-03-01T23:54:22Z | |
dc.date.available | 2018-03-01T23:54:22Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/5829 | |
dc.description.abstract | Ru-doped SnO2 powder, (RuxSn1-x)O-2, with a Sn:Ru atomic ratio of 9:1 was synthesized and used as a support for Pt nanoparticles (30 mass % loading). The (RuxSn1-x)O-2 support and the Pt/(RuxSn1-x)O-2 catalyst were characterized by X-ray diffraction measurements, energy dispersive X-ray spectroscopy and transmission electron microscopy (TEM). The (RuxSn1-x)O-2 was found to be a two-phase material consisting of probably a solid solution of RuO2 in SnO2 and pure RuO2. The average Pt particle size determined by TEM was 5.3 nm. Cyclic voltammetry of Pt/(RuxSn1-x)O-2 indicated good conductivity of the support and displayed the usual features of Pt. The results of the electrochemical oxidation of COad, and methanol on Pt/(RuxSn1-x)O-2 were compared with those on commercial Pt/C and PtRu/C catalysts. Oxidation of COads on Pt/(RuxSn1-x)O-2 starts at lower positive potentials than on PtRu/C and Pt/C. Potentiodynamic polarization curves and chronoamperometric curves of methanol oxidation indicated higher initial activity of the Pt/(RuxSn1-x)O-2 catalyst compared to PtRu/C, but also a greater loss in current density over time. A potentiodynamic stability test of the catalysts revealed that deactivation of Pt/(RuxSn1-x)O-2 and Pt/C was primarily caused by poisoning of the Pt surface by residues of methanol oxidation, which mostly occurred during the first potential cycle. In the case of PtRu/C, the poisoning of the surface was minor and deactivation was caused by surface area loss of the PtRu. | en |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172054/RS// | |
dc.rights | openAccess | en |
dc.source | Journal of the Serbian Chemical Society | en |
dc.subject | methanol oxidation | en |
dc.subject | CO oxidation | en |
dc.subject | platinum | en |
dc.subject | Ru-doped SnO2 | en |
dc.subject | electrocatalysis | en |
dc.subject | fuel cell | en |
dc.title | Electrochemical oxidation of methanol on Pt/(RuxSn1-x)O-2 nanocatalyst | en |
dc.type | article | en |
dcterms.abstract | Крстајиц, Мила Н.; Обрадовиц, Маја Д.; Бабиц, Биљана М.; Радмиловиц, Велимир Р.; Крстајиц, Недељко В.; Гојковиц, Снезана Љ.; Лацњевац, Урос Ц.; | |
dc.citation.volume | 78 | |
dc.citation.issue | 11 | |
dc.citation.spage | 1703 | |
dc.citation.epage | 1716 | |
dc.identifier.wos | 000329265400007 | |
dc.identifier.doi | 10.2298/JSC130718091K | |
dc.citation.rank | M23 | |
dc.identifier.scopus | 2-s2.0-84888124242 | |
dc.identifier.fulltext | https://vinar.vin.bg.ac.rs//bitstream/id/13575/5825.pdf |