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Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide

dc.creatorPejović, Anka
dc.creatorDamljanović, Ivan S.
dc.creatorStevanović, Dragana D.
dc.creatorIlic, Danijela
dc.creatorVukićević, Mirjana
dc.creatorBogdanović, Goran A.
dc.creatorVukićević, Rastko D.
dc.date.accessioned2018-03-01T23:36:25Z
dc.date.available2018-03-01T23:36:25Z
dc.date.issued2013
dc.identifier.issn0040-4039
dc.identifier.urihttps://vinar.vin.bg.ac.rs/handle/123456789/5623
dc.description.abstractDimethyl(2-ferrocenoylethyl)sulfonium iodide was synthesized by reacting 1-ferroceny1-4-thiapentan-1-one with iodomethane and characterized from spectral data and single crystal X-ray structure analysis. This compound was capable of reacting with different N-, S-, and O-nucleophiles giving the corresponding beta-functionalized ferrocene-containing ketones. Furthermore, dimethyl sulfide can be displaced from the dimethyl(2-ferrocenoylethyl)sulfonium ion with cyanide or carbanions derived from 1,3-bifunctional compounds and nitropropane, leading to products with a new carbon-carbon bond. (C) 2013 Elsevier Ltd. All rights reserved.en
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172034/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS//
dc.rightsrestrictedAccessen
dc.sourceTetrahedron Lettersen
dc.subjectFerroceneen
dc.subjectSulfonium salten
dc.subjectNucleophilic substitutionen
dc.subjectbeta-Functionalized ferrocenyl ketonesen
dc.subject1,3-Dicarbonylsen
dc.subjectX-ray analysisen
dc.titleSynthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodideen
dc.typearticleen
dcterms.abstractВукицевиц, Мирјана; Пејовиц, Aнка; Дамљановиц, Иван; Илиц, Данијела; Вукицевиц, Растко Д.; Стевановиц, Драгана; Богдановић Горан;
dc.citation.volume54
dc.citation.issue35
dc.citation.spage4776
dc.citation.epage4780
dc.identifier.wos000323020400044
dc.identifier.doi10.1016/j.tetlet.2013.06.130
dc.citation.rankM22
dc.identifier.scopus2-s2.0-84880839901


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