Приказ основних података о документу
Benzimidazole derivatives as NSO ligands for the fac-[M(CO)(3)](+) (M = Re, Tc-99m)
dc.creator | Tsotakos, T. | |
dc.creator | Tsoukalas, C. | |
dc.creator | Patsis, G. | |
dc.creator | Panagiotopoulou, A. | |
dc.creator | Nikolić, Nadežda S. | |
dc.creator | Janković, Drina | |
dc.creator | Đokić, Divna Đ. | |
dc.creator | Raptopoulou, C. P. | |
dc.creator | Terzis, A. | |
dc.creator | Papagiannopoulou, D. | |
dc.creator | Pelecanou, M. | |
dc.creator | Papadopoulos, M. | |
dc.creator | Pirmettis, Ioannis | |
dc.date.accessioned | 2018-03-01T22:04:00Z | |
dc.date.available | 2018-03-01T22:04:00Z | |
dc.date.issued | 2011 | |
dc.identifier.issn | 0020-1693 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/4546 | |
dc.description.abstract | Two rhenium(I) tricarbonyl complexes with the tridentate monoanionic NSO ligands, 4-(benzimidazol-2-yl)-3-thiabutanoic acid (complex 3) and [1-(11-carboxyundecanyl)-4-(benzimidazol-2-yl)]-3-thiabutanoic acid (complex 4) were synthesized and characterized by spectroscopic methods and elemental analysis. X-ray crystallographic analysis of complex 3 revealed a distorted octahedral geometry around rhenium defined by the three facially bound CO groups and the NSO donor atom set of the tridentate ligand. The analogous technetium-99m complexes (complexes 5 and 6) were also prepared quantitatively by reaction of the NSO ligands with the fac-[Tc-99m(H2O)(3)(CO)(3)](+) synthon and their identity was established by chromatographic comparison to their rhenium congeners. Biodistribution in mice of complex 6 bearing the fatty acid chain showed significant heart uptake (6.26 +/- 0.79% ID/g p.i.) at 1 min accompanied, however, with a heart: blood ratio below 1. (C) 2011 Elsevier B. V. All rights reserved. | en |
dc.relation | GSRT, Hellenic Ministry of Development, Greek-Serbian Bilateral Co-operation Research Project [709] | |
dc.rights | restrictedAccess | en |
dc.source | Inorganica Chimica Acta | en |
dc.subject | Technetium-99m | en |
dc.subject | Rhenium | en |
dc.subject | Tricarbonyl | en |
dc.subject | Fatty acid | en |
dc.title | Benzimidazole derivatives as NSO ligands for the fac-[M(CO)(3)](+) (M = Re, Tc-99m) | en |
dc.type | article | en |
dcterms.abstract | Тсотакос, Т.; Пелецаноу, М.; Папагианнопоулоу, Д.; Терзис, A.; Раптопоулоу, Ц. П.; Дјокиц, Д.; Панагиотопоулоу, A.; Патсис, Г.; Тсоукалас, Ц.; Јанковић Дрина; Пирметтис, И.; Николиц, Н.; Пападопоулос, М.; | |
dc.citation.volume | 377 | |
dc.citation.issue | 1 | |
dc.citation.spage | 62 | |
dc.citation.epage | 68 | |
dc.identifier.wos | 000296523400010 | |
dc.identifier.doi | 10.1016/j.ica.2011.07.035 | |
dc.citation.rank | M23 | |
dc.identifier.scopus | 2-s2.0-80053921602 |
Документи
Датотеке | Величина | Формат | Преглед |
---|---|---|---|
Уз овај запис нема датотека. |