Synthesis and characterization of Cu-doped ceria nanopowders
Babić, Biljana M.
Dohcevic-Mitrovic, Z. D.
Radović, Marko B.
Popović, Zoran V.
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Nanopowdered solid solution Ce(1-x)Cu(x)O(2-gamma) samples (0 LT = x LT = 0.15) were synthesized by self-propagating room temperature synthesis (SPRT). Raman spectroscopy and XRD at room temperature were used to study the vibration properties of these materials as well as the Cu solubility in ceria lattice. The solubility limit of Cu(2+) in CeO(2) lattice was found to be lower than published in the literature. Results show that obtained powders with low dopant concentration are solid solutions with a fluorite-type crystal structure. However, with Cu content higher than 7.5 mass%, the phase separation was observed and two oxide phases, CeO(2) and CuO, coexist. All powders were nanometric in size with high specific surface area. (C) 2011 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
Кључне речи:CeO(2) / Solid solution / Raman spectroscopy / XRD measurements
Извор:Ceramics International, 2011, 37, 8, 3161-3165
- Синтеза, процесирање и карактеризација наноструктурних материјала за примену у области енергије, механичког инжењерства, заштите животне стредине и биомедицине (RS-45012)
ISSN: 0272-8842 (print)