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dc.creatorVodnik, Vesna
dc.creatorBožanić, Dušan K.
dc.creatorDžunuzović, Enis S.
dc.creatorVuković, Jasna V.
dc.creatorNedeljković, Jovan
dc.date.accessioned2018-03-01T21:06:17Z
dc.date.available2018-03-01T21:06:17Z
dc.date.issued2010
dc.identifier.issn0014-3057
dc.identifier.urihttps://vinar.vin.bg.ac.rs/handle/123456789/3916
dc.description.abstractSurface modified silver nanoparticles dispersed in chloroform were encapsulated in poly(methylmethacrylate) (PMMA) by in-situ radical polymerization of methyl methacrylate initiated by 2,2-azobisisobutyronitrile. The particle size distribution of colloidal silver nanoparticles was determined using transmission electron microscopy. The obtained transparent nanocomposite films were characterized using UV-vis spectroscopy, (1)H NMR spectroscopy and gel permeation chromatography. Effective medium Maxwell-Garnett theory was used in order to explain optical properties of nanocomposite films taking into account inhomogeneous spatial distribution of silver nanoparticles in PMMA matrix. The influence of the silver nanoparticles on the thermal properties of the PMMA matrix was investigated using thermo-gravimetric analysis and differential scanning calorimetry. Thermo-oxidative stability of the PMMA in the presence of low content of inorganic phase is significantly improved. The glass transition temperatures of nanocomposites are slightly lower compared to the pure polymer. (C) 2009 Elsevier Ltd. All rights reserved.en
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142066/RS//
dc.rightsrestrictedAccessen
dc.sourceEuropean Polymer Journalen
dc.subjectSilver nanoparticlesen
dc.subjectPMMAen
dc.subjectNanocompositeen
dc.subjectIn-situ radical polymerizationen
dc.subjectMaxwell-Garnet theoryen
dc.subjectThermal stabilityen
dc.titleThermal and optical properties of silver-poly(methylmethacrylate) nanocomposites prepared by in-situ radical polymerizationen
dc.typearticleen
dcterms.abstractДзунузовиц, Е.; Вуковиц, Ј.; Водник Весна; Бозанић Душан; Недељковић Јован;
dc.citation.volume46
dc.citation.issue2
dc.citation.spage137
dc.citation.epage144
dc.identifier.wos000274844800001
dc.identifier.doi10.1016/j.eurpolymj.2009.10.022
dc.citation.rankM21
dc.identifier.scopus2-s2.0-73849093408


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