Inapplicability of Small-Polaron Model for the Explanation of Infrared Absorption Spectrum in Acetanilide
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The applicability of small-polaron model for the interpretation of infrared absorption spectrum in acetanilide has been critically reexamined. It is shown that the energy difference between the normal and anomalous peak. calculated by means of small-polaron theory, displays pronounced temperature dependence which is in drastic contradiction with experiment. It is demonstrated that se l-trapped states, which are recently suggested to explain theoretically the experimental absorption spectrum in protein, cannot cause the appearance of the peaks in absorption spectrum for acetanilide.
Кључне речи:Infrared absorption spectrum / Acetanilide / Protein / Small-polaron model
Извор:Electromagnetic Biology and Medicine, 2009, 28, 2, 182-187
- Serbian Ministry of Science and Technology