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dc.creatorIvkovic, Sonja A.
dc.creatorVojinović-Ješić, Ljiljana S.
dc.creatorLeovac, Vukadin M.
dc.creatorRodic, Marko V.
dc.creatorNovaković, Slađana B.
dc.creatorBogdanović, Goran A.
dc.date.accessioned2018-03-01T15:51:49Z
dc.date.available2018-03-01T15:51:49Z
dc.date.issued2015
dc.identifier.issn1040-0400 (print)
dc.identifier.issn1572-9001 (electronic)
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/360
dc.description.abstractA novel pyridoxal thiosemicarbazone (PLTSC) compound, exhibiting ligating properties, of the formula PLTSC center dot HCl center dot 2H(2)O (1) was synthesized and characterized by X-ray analysis. The PLTSC ligand 1 displays significantly different conformation in comparison to the five previously reported compounds of this type. The structural properties of six PLTSC ligands in different conformations were compared in order to establish the structural differences and understand the factors that facilitate particular conformations. The analysis indicated great structural flexibility of the PLTSC ligands. The PLTSC ligand 1 is essentially a planar molecule with the r.m.s deviation of all non-H atoms equal to 0.06 angstrom. Consequently, the molecules of 1 form a layered three-dimensional structure which is stabilized by a variety of hydrogen bonds: O-H center dot center dot center dot O, O-H center dot center dot center dot N, O-H center dot center dot center dot Cl, O-H center dot center dot center dot S, N-H center dot center dot center dot O, N-H center dot center dot center dot N, N-H center dot center dot center dot Cl, N-H center dot center dot center dot S. In addition, the crystal structure of the Fe(III) complex with the ligand 1 of the formula [Fe(PLTSC)Cl-2(H2O)]Cl was resolved by single-crystal X-ray analysis and structural properties of this octahedral complex were discussed and compared to those of uncoordinated PLTSC ligand.en
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172014/RS//
dc.relationProvincial Secretariat for Science and Technological Development of Vojvodina
dc.rightsrestrictedAccessen
dc.sourceStructural Chemistryen
dc.subjectPyridoxal thiosemicarbazoneen
dc.subjectFe(III) complexen
dc.subjectCrystal structuresen
dc.subjectComparative studyen
dc.titleTransition metal complexes with thiosemicarbazide-based ligands. Part 61. Comparative analysis of structural properties of the pyridoxal thiosemicarbazone ligands. Crystal structure of PLTSC center dot HCl center dot 2H(2)O and its complex [Fe(PLTSC)Cl-2(H2O)]Clen
dc.typearticleen
dcterms.abstractНоваковић Слађана; Родиц, Марко В.; Војиновиц-Јесиц, Љиљана С.; Леовац, Вукадин М.; Ивковиц, Соња A.; Богдановић Горан;
dc.citation.volume26
dc.citation.issue1
dc.citation.spage269
dc.citation.epage277
dc.identifier.wos000347954800027
dc.identifier.doi10.1007/s11224-014-0491-6
dc.citation.rankM22
dc.identifier.scopus2-s2.0-84939888010


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