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The batch study of Sr2+ sorption by bone char
dc.creator | Smičiklas, Ivana D. | |
dc.creator | Dimović, Slavko | |
dc.creator | Šljivić-Ivanović, Marija Z. | |
dc.creator | Plećaš, Ilija B. | |
dc.date.accessioned | 2018-03-01T20:16:48Z | |
dc.date.available | 2018-03-01T20:16:48Z | |
dc.date.issued | 2008 | |
dc.identifier.issn | 1093-4529 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/3343 | |
dc.description.abstract | Considering the excellent sorption properties of synthetic calcium hydroxyapatite (HAP) towards many divalent cations, the potential application of bone char, the natural source of HAP, for sequestering Sr(2+)ions from aqueous solutions has been studied in batch conditions. Contact time, initial solution pH and initial Sr2+ concentrations were varied to examine the effect of these process parameters on the amount of Sr2+ sorbed. The kinetics of Sr2+ sorption was found to be a 2-step process, with contact time of 24 h required for attaining equilibrium. The sorption isotherm was well fitted with Langmuir and DKR theoretical models. Sorption of Sr2+ on bone char was found to be a favorable, thermodynamically feasible and spontaneous process, with the maximum sorption capacity of 0.271 mmol/g and sorption energy of 11.09 kJ/mol. The sorption was pH-independent in the initial pH range 4-10, as a result of excellent buffering properties of bone char (constant final pH), while for pH GT 10 sorbed amounts of Sr2+ increased due to attractive electrostatic forces between negatively charged sorbent surface and positively charged metal ions. On the basis of the amount of Ca2+ released and final pH decrease in respect to the point of zero charge of bone char (pHPZC), two possible mechanisms of Sr2+ sorption were identified: ion-exchange and the formation of complex compounds with HAP and carbon active surface sites. The amounts of Sr2+ leached from bone char increased with the increase of Ca2+ content and the decrease of solution pH. In comparison with synthetic HAP, bone char represents a cost-effective alternative for Sr2+ sequestering. | en |
dc.rights | restrictedAccess | en |
dc.source | Journal of Environmental Science and Health. Part A: Toxic Hazardous Substances and Environmental Engineering | en |
dc.subject | bone char | en |
dc.subject | Sr2+ | en |
dc.subject | sorption | en |
dc.subject | sorption mechanisms | en |
dc.subject | equilibrium | en |
dc.subject | kinetic | en |
dc.title | The batch study of Sr2+ sorption by bone char | en |
dc.type | article | en |
dcterms.abstract | Плецас, И.; Смициклас Ивана; Димовић Славко; Шљивић-Ивановић Марија; | |
dc.citation.volume | 43 | |
dc.citation.issue | 2 | |
dc.citation.spage | 210 | |
dc.citation.epage | 217 | |
dc.identifier.wos | 000252344200013 | |
dc.identifier.doi | 10.1080/10934520701781624 | |
dc.citation.rank | M23 | |
dc.identifier.pmid | 18172814 | |
dc.identifier.scopus | 2-s2.0-37849041365 |
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