Experimental and theoretical investigation of new hypervalent molecules LinF (n=2-4)
Koteski, Vasil J.
Đorđević, Vesna R.
Cvetićanin, Jelena M.
Đustebek, Jasmina B.
Veljković, Miomir V.
Neskovic, Olivera M.
Чланак у часопису
МетаподациПриказ свих података о документу
Hypervalent molecules of Li3F and Li4F were detected experimentally for the first time. Ionization energies determined by the thermal ionization mass spectrometry were 3.8 +/- 0.2 eV for Li2F, 4.0 +/- 0.2 eV for Li3F and 3.9 +/- 0.2 eV for Li4F. The ionization energies obtained by ab initio calculations support the experimental findings. The lowest energy structures of the LinF (n = 2-4) molecules and their cations were also predicted. (C) 2007 Elsevier B.V. All rights reserved.
Извор:Chemical Physics Letters, 2007, 448, 4-6, 151-155
ISSN: 0009-2614 (print)