Rare Pb-Bi sulfosalt mineralization from the Boranja orefield (Podrinje district, Serbia)
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Аутори
Radosavljević-Mihajlović, Ana S.Stojanovic, Jovica N.
Dimitrijevic, Radovan Z.
Radosavljevic, Slobodan A.
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Pb-Bi sulfosalts are uncommon minerals in the deposits and mineralization of Boranja orefield (West Serbia), one of the less-known Serbian ore deposits. In the Kram locality the Pb-Bi sulfosalts occur typically in skarns associated with garnet, epidote, calcite and magnetite. Pyrrhotite, chalcopyrite, chalcopyrrhotite, valerite, tetradymite, native bismuth, native gold are associated with sulfide phases. Furthermore, the electron microprobe analyses of the Pb-Bi sulfosalts yielded empirical formulae: bursaite (Pb4.81Fe0.03CU0.08Ag0.16)(Sigma 5.08)Bi-3.87(S10.99Te0.06)(Sigma 11.05), Cannizzarite (Pb3.05Ag0.02)(Sigma 3.07)Bi4.00S8.93 cosalite (Pb-1.95,Cu-0.08)(Sigma 2.03)(Bi1.92Sb0.01) S-Sigma 1.93(5.05); aikinite (Cu-0.97,Fe-0.02)(Sigma 0.99)(Pb0.9Ag0.05)(Sigma 1.03)Bi0.95S3.03, All of the Pb-Bi sulfosalts have Bi/Pb atomic ratio in the range 0.8-1.3. Unit-cell parameters were calculated for bursaite and cannizzarite. Orthorhombic unit-cell parameters for bursaite amount to: a = 4.106(5...); b = 13.42(2); c = 20.50(3) angstrom; V = 1129.7(2) angstrom(3). The strongest reflections in the X-ray powder diffraction pattern are [d(in angstrom)(I)]: 3.456(100), 3.407(90), and 3.550(56). Monoclinic unit-cell parameters for cannizzarite (Q-subcell) amount to: a = 15.560(6); b = 4.105(2); c = 4.125(1) angstrom; beta = 100.78(2); V = 258.8(1) angstrom(3); and for the H-subcell to: a = 15.470(9); b = 4.096(2); c = 7.000(5) angstrom; beta= 98.53(5); V = 438.3(3) angstrom(3). The strongest reflections in the X-ray powder diffraction pattern are: 3.821(88), 3.337(62), and 3.009(61).
Кључне речи:
Pb-Bi sulfosalts / bursaite / cannizzarite / cosalite / aikinite / Boranja orefield / Podrinje district / SerbiaИзвор:
Neues Jahrbuch Fur Mineralogie. Abhandlungen, 2007, 184, 2, 217-224
DOI: 10.1127/0077-7757/2007/0094
ISSN: 0077-7757
WoS: 000250952600009
Scopus: 2-s2.0-36248945539
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Институција/група
VinčaTY - JOUR AU - Radosavljević-Mihajlović, Ana S. AU - Stojanovic, Jovica N. AU - Dimitrijevic, Radovan Z. AU - Radosavljevic, Slobodan A. PY - 2007 UR - https://vinar.vin.bg.ac.rs/handle/123456789/3316 AB - Pb-Bi sulfosalts are uncommon minerals in the deposits and mineralization of Boranja orefield (West Serbia), one of the less-known Serbian ore deposits. In the Kram locality the Pb-Bi sulfosalts occur typically in skarns associated with garnet, epidote, calcite and magnetite. Pyrrhotite, chalcopyrite, chalcopyrrhotite, valerite, tetradymite, native bismuth, native gold are associated with sulfide phases. Furthermore, the electron microprobe analyses of the Pb-Bi sulfosalts yielded empirical formulae: bursaite (Pb4.81Fe0.03CU0.08Ag0.16)(Sigma 5.08)Bi-3.87(S10.99Te0.06)(Sigma 11.05), Cannizzarite (Pb3.05Ag0.02)(Sigma 3.07)Bi4.00S8.93 cosalite (Pb-1.95,Cu-0.08)(Sigma 2.03)(Bi1.92Sb0.01) S-Sigma 1.93(5.05); aikinite (Cu-0.97,Fe-0.02)(Sigma 0.99)(Pb0.9Ag0.05)(Sigma 1.03)Bi0.95S3.03, All of the Pb-Bi sulfosalts have Bi/Pb atomic ratio in the range 0.8-1.3. Unit-cell parameters were calculated for bursaite and cannizzarite. Orthorhombic unit-cell parameters for bursaite amount to: a = 4.106(5); b = 13.42(2); c = 20.50(3) angstrom; V = 1129.7(2) angstrom(3). The strongest reflections in the X-ray powder diffraction pattern are [d(in angstrom)(I)]: 3.456(100), 3.407(90), and 3.550(56). Monoclinic unit-cell parameters for cannizzarite (Q-subcell) amount to: a = 15.560(6); b = 4.105(2); c = 4.125(1) angstrom; beta = 100.78(2); V = 258.8(1) angstrom(3); and for the H-subcell to: a = 15.470(9); b = 4.096(2); c = 7.000(5) angstrom; beta= 98.53(5); V = 438.3(3) angstrom(3). The strongest reflections in the X-ray powder diffraction pattern are: 3.821(88), 3.337(62), and 3.009(61). T2 - Neues Jahrbuch Fur Mineralogie. Abhandlungen T1 - Rare Pb-Bi sulfosalt mineralization from the Boranja orefield (Podrinje district, Serbia) VL - 184 IS - 2 SP - 217 EP - 224 DO - 10.1127/0077-7757/2007/0094 ER -
@article{ author = "Radosavljević-Mihajlović, Ana S. and Stojanovic, Jovica N. and Dimitrijevic, Radovan Z. and Radosavljevic, Slobodan A.", year = "2007", abstract = "Pb-Bi sulfosalts are uncommon minerals in the deposits and mineralization of Boranja orefield (West Serbia), one of the less-known Serbian ore deposits. In the Kram locality the Pb-Bi sulfosalts occur typically in skarns associated with garnet, epidote, calcite and magnetite. Pyrrhotite, chalcopyrite, chalcopyrrhotite, valerite, tetradymite, native bismuth, native gold are associated with sulfide phases. Furthermore, the electron microprobe analyses of the Pb-Bi sulfosalts yielded empirical formulae: bursaite (Pb4.81Fe0.03CU0.08Ag0.16)(Sigma 5.08)Bi-3.87(S10.99Te0.06)(Sigma 11.05), Cannizzarite (Pb3.05Ag0.02)(Sigma 3.07)Bi4.00S8.93 cosalite (Pb-1.95,Cu-0.08)(Sigma 2.03)(Bi1.92Sb0.01) S-Sigma 1.93(5.05); aikinite (Cu-0.97,Fe-0.02)(Sigma 0.99)(Pb0.9Ag0.05)(Sigma 1.03)Bi0.95S3.03, All of the Pb-Bi sulfosalts have Bi/Pb atomic ratio in the range 0.8-1.3. Unit-cell parameters were calculated for bursaite and cannizzarite. Orthorhombic unit-cell parameters for bursaite amount to: a = 4.106(5); b = 13.42(2); c = 20.50(3) angstrom; V = 1129.7(2) angstrom(3). The strongest reflections in the X-ray powder diffraction pattern are [d(in angstrom)(I)]: 3.456(100), 3.407(90), and 3.550(56). Monoclinic unit-cell parameters for cannizzarite (Q-subcell) amount to: a = 15.560(6); b = 4.105(2); c = 4.125(1) angstrom; beta = 100.78(2); V = 258.8(1) angstrom(3); and for the H-subcell to: a = 15.470(9); b = 4.096(2); c = 7.000(5) angstrom; beta= 98.53(5); V = 438.3(3) angstrom(3). The strongest reflections in the X-ray powder diffraction pattern are: 3.821(88), 3.337(62), and 3.009(61).", journal = "Neues Jahrbuch Fur Mineralogie. Abhandlungen", title = "Rare Pb-Bi sulfosalt mineralization from the Boranja orefield (Podrinje district, Serbia)", volume = "184", number = "2", pages = "217-224", doi = "10.1127/0077-7757/2007/0094" }
Radosavljević-Mihajlović, A. S., Stojanovic, J. N., Dimitrijevic, R. Z.,& Radosavljevic, S. A.. (2007). Rare Pb-Bi sulfosalt mineralization from the Boranja orefield (Podrinje district, Serbia). in Neues Jahrbuch Fur Mineralogie. Abhandlungen, 184(2), 217-224. https://doi.org/10.1127/0077-7757/2007/0094
Radosavljević-Mihajlović AS, Stojanovic JN, Dimitrijevic RZ, Radosavljevic SA. Rare Pb-Bi sulfosalt mineralization from the Boranja orefield (Podrinje district, Serbia). in Neues Jahrbuch Fur Mineralogie. Abhandlungen. 2007;184(2):217-224. doi:10.1127/0077-7757/2007/0094 .
Radosavljević-Mihajlović, Ana S., Stojanovic, Jovica N., Dimitrijevic, Radovan Z., Radosavljevic, Slobodan A., "Rare Pb-Bi sulfosalt mineralization from the Boranja orefield (Podrinje district, Serbia)" in Neues Jahrbuch Fur Mineralogie. Abhandlungen, 184, no. 2 (2007):217-224, https://doi.org/10.1127/0077-7757/2007/0094 . .