Transition metal complexes with thiosemicarbazide-based ligands. Part LVI: Nickel(II) complex with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone and unusually deformed coordination geometry
Нема приказа
Аутори
Leovac, Vukadin M.Novaković, Slađana B.
Bogdanović, Goran A.
Joksović, Milan D.
Szecsenyi, Katalin Meszaros
Češljević, Valerija I.
Чланак у часопису
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Приказ свих података о документуАпстракт
Synthesis of a new nickel(II) complex, [Ni(Ph(2)PzTSC-H)(2)] with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone (Ph(2)PzTSC), is described. The compounds have been characterized by elemental and thermal analysis, molar conductivity and spectral (UV-Vis, IR, H-1 NMR, and C-13 NMR) measurements. In the case of complex the magnetic measurement has been also performed. Crystal and molecular structures of both the free ligand and the complex have been determined by single crystal X-ray analysis. It was found that the ligand coordinates in a bidentate NS fashion, in its deprotonated thioenolato form. The cis-square-planar geometry of the complex is significantly distorted tetrahedrally. The Cambridge Structural Database (CSD) study has been performed to obtain geometrical and structural informations on similar nickel(II) complexes in order to compare structural data. (c) 2007 Elsevier Ltd. All rights reserved.
Кључне речи:
Nickel(II) complex / thiosemicarbazone / spectroscopic and TA studies / crystal structure / CSD studyИзвор:
Polyhedron, 2007, 26, 14, 3783-3792
DOI: 10.1016/j.poly.2007.04.012
ISSN: 0277-5387
WoS: 000249714200032
Scopus: 2-s2.0-34547813765
Колекције
Институција/група
VinčaTY - JOUR AU - Leovac, Vukadin M. AU - Novaković, Slađana B. AU - Bogdanović, Goran A. AU - Joksović, Milan D. AU - Szecsenyi, Katalin Meszaros AU - Češljević, Valerija I. PY - 2007 UR - https://vinar.vin.bg.ac.rs/handle/123456789/3284 AB - Synthesis of a new nickel(II) complex, [Ni(Ph(2)PzTSC-H)(2)] with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone (Ph(2)PzTSC), is described. The compounds have been characterized by elemental and thermal analysis, molar conductivity and spectral (UV-Vis, IR, H-1 NMR, and C-13 NMR) measurements. In the case of complex the magnetic measurement has been also performed. Crystal and molecular structures of both the free ligand and the complex have been determined by single crystal X-ray analysis. It was found that the ligand coordinates in a bidentate NS fashion, in its deprotonated thioenolato form. The cis-square-planar geometry of the complex is significantly distorted tetrahedrally. The Cambridge Structural Database (CSD) study has been performed to obtain geometrical and structural informations on similar nickel(II) complexes in order to compare structural data. (c) 2007 Elsevier Ltd. All rights reserved. T2 - Polyhedron T1 - Transition metal complexes with thiosemicarbazide-based ligands. Part LVI: Nickel(II) complex with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone and unusually deformed coordination geometry VL - 26 IS - 14 SP - 3783 EP - 3792 DO - 10.1016/j.poly.2007.04.012 ER -
@article{ author = "Leovac, Vukadin M. and Novaković, Slađana B. and Bogdanović, Goran A. and Joksović, Milan D. and Szecsenyi, Katalin Meszaros and Češljević, Valerija I.", year = "2007", abstract = "Synthesis of a new nickel(II) complex, [Ni(Ph(2)PzTSC-H)(2)] with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone (Ph(2)PzTSC), is described. The compounds have been characterized by elemental and thermal analysis, molar conductivity and spectral (UV-Vis, IR, H-1 NMR, and C-13 NMR) measurements. In the case of complex the magnetic measurement has been also performed. Crystal and molecular structures of both the free ligand and the complex have been determined by single crystal X-ray analysis. It was found that the ligand coordinates in a bidentate NS fashion, in its deprotonated thioenolato form. The cis-square-planar geometry of the complex is significantly distorted tetrahedrally. The Cambridge Structural Database (CSD) study has been performed to obtain geometrical and structural informations on similar nickel(II) complexes in order to compare structural data. (c) 2007 Elsevier Ltd. All rights reserved.", journal = "Polyhedron", title = "Transition metal complexes with thiosemicarbazide-based ligands. Part LVI: Nickel(II) complex with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone and unusually deformed coordination geometry", volume = "26", number = "14", pages = "3783-3792", doi = "10.1016/j.poly.2007.04.012" }
Leovac, V. M., Novaković, S. B., Bogdanović, G. A., Joksović, M. D., Szecsenyi, K. M.,& Češljević, V. I.. (2007). Transition metal complexes with thiosemicarbazide-based ligands. Part LVI: Nickel(II) complex with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone and unusually deformed coordination geometry. in Polyhedron, 26(14), 3783-3792. https://doi.org/10.1016/j.poly.2007.04.012
Leovac VM, Novaković SB, Bogdanović GA, Joksović MD, Szecsenyi KM, Češljević VI. Transition metal complexes with thiosemicarbazide-based ligands. Part LVI: Nickel(II) complex with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone and unusually deformed coordination geometry. in Polyhedron. 2007;26(14):3783-3792. doi:10.1016/j.poly.2007.04.012 .
Leovac, Vukadin M., Novaković, Slađana B., Bogdanović, Goran A., Joksović, Milan D., Szecsenyi, Katalin Meszaros, Češljević, Valerija I., "Transition metal complexes with thiosemicarbazide-based ligands. Part LVI: Nickel(II) complex with 1,3-diphenylpyrazole-4-carboxaldehyde thiosemicarbazone and unusually deformed coordination geometry" in Polyhedron, 26, no. 14 (2007):3783-3792, https://doi.org/10.1016/j.poly.2007.04.012 . .