Show simple item record

dc.creatorSredojević, Dušan
dc.creatorBogdanović, Goran A.
dc.creatorTomić, Zoran D.
dc.creatorZaric, Snezana D.
dc.date.accessioned2018-03-01T20:10:46Z
dc.date.available2018-03-01T20:10:46Z
dc.date.issued2007
dc.identifier.issn1466-8033 (print)
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/3272
dc.description.abstractThe crystal structures of square-planar transition-metal complexes from the Cambridge Structural Database (CSD) with close contacts between planar chelate rings and aryl rings containing six carbon atoms (C-6- aryl) were analyzed. Most of the chelate rings in these structures are fused with aromatic or other pi-delocalized chelate rings. The results show that planar chelate rings can be involved in stacking and CH-pi interactions with organic aryl rings. However, the number of stacking interactions is a few times larger than the number of CH-pi interactions. The analysis also shows that in almost all cases CH-pi interactions are formed only when stacking interactions are prevented by voluminous substituents. Hence, between planar chelate rings and C-6- aryl rings stacking interactions are preferred to CH-pi interactions.en
dc.rightsrestrictedAccessen
dc.sourceCrystEngCommen
dc.titleStacking vs. CH-pi interactions between chelate and aryl rings in crystal structures of square-planar transition metal complexesen
dc.typearticleen
dcterms.abstractСредојевић Душан; Богдановић Горан; Томић Зоран; Зариц, Снезана Д.;
dc.citation.volume9
dc.citation.issue9
dc.citation.spage793
dc.citation.epage798
dc.identifier.wos000249078700022
dc.identifier.doi10.1039/b704302c
dc.citation.rankM21
dc.identifier.scopus2-s2.0-34548232165


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record