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Transition metal complexes with Girard reagent-based ligands. Part III. Synthesis and characterization of salicylaldehyde Girard-T hydrazone complexes. Crystal structure of ligand and two isostructural copper(II) complexes
dc.creator | Leovac, Vukadin M. | |
dc.creator | Bogdanović, Goran A. | |
dc.creator | Češljević, Valerija I. | |
dc.creator | Jovanović, Ljiljana S. | |
dc.creator | Novaković, Slađana B. | |
dc.creator | Vojinović-Ješić, Ljiljana S. | |
dc.date.accessioned | 2018-03-01T20:00:41Z | |
dc.date.available | 2018-03-01T20:00:41Z | |
dc.date.issued | 2007 | |
dc.identifier.issn | 1040-0400 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/3154 | |
dc.description.abstract | The ligand, salicylaldehyde Girard-T hydrazonium chloride, [H(2)SalGT]Cl (1), and two complexes [Cu(HSalGT)X-2]center dot H2O (X = Br(2); Cl(3)) were synthesized and their crystal structures were determined by single-crystal X-ray analysis. In the two isostructural complexes, the Cu(II) is located in a square-pyramidal environment, with the chelating ligand and one halogen atom in the basal plane and the second halogen in the apical position. The most apparent structural difference between the 1 and its complexes 2 and 3 is the orientation of the N(CH3)(3) group: in 1, it is practically coplanar to the rest of the molecule, while in 2 and 3 it is oriented to the side of the axially bonded halogen, which can be explained by the C-H center dot center dot center dot X intramolecular interactions. The compounds were characterized by elemental analysis, molar conductivity, magnetic susceptibility and electronic absorption spectra. | en |
dc.publisher | Springer | |
dc.relation | info:eu-repo/grantAgreement/MESTD/MPN2006-2010/142010/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/MPN2006-2010/142028/RS// | |
dc.rights | restrictedAccess | en |
dc.source | Structural Chemistry | en |
dc.subject | Girard-T reagent-based ligand | en |
dc.subject | Cu(II) complexes | en |
dc.subject | crystal structures | en |
dc.subject | electronic absorption spectra | en |
dc.title | Transition metal complexes with Girard reagent-based ligands. Part III. Synthesis and characterization of salicylaldehyde Girard-T hydrazone complexes. Crystal structure of ligand and two isostructural copper(II) complexes | en |
dc.type | article | en |
dc.rights.license | ARR | |
dcterms.abstract | Јовановиц, Љиљана С.; Леовац, Вукадин М.; Цесљевиц, Валерија И.; Војиновиц-Јесиц, Љиљана С.; Богдановић Горан; Новаковић Слађана; | |
dc.citation.volume | 18 | |
dc.citation.issue | 1 | |
dc.citation.spage | 113 | |
dc.citation.epage | 119 | |
dc.identifier.wos | 000244148100017 | |
dc.identifier.doi | 10.1007/s11224-006-9136-8 | |
dc.citation.rank | M23 | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-33846821934 |