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Transition metal complexes with thiosemicarbazide-based ligands. LIII. [4-(2-diphenylphosphino-alpha-ethoxybenzyl-kappa P)-S-methyl-1-(4-oxidopent-3-en-4-ylidene-kappa O)-thiosemicarbazido-kappa(2) N-1, N-4]nickel (II)
dc.creator | Drašković, Bojana M. | |
dc.creator | Bogdanović, Goran A. | |
dc.creator | Leovac, Vukadin M. | |
dc.creator | Brceski, Ilija D. | |
dc.creator | Poleti, Dejan | |
dc.date.accessioned | 2018-03-01T19:50:44Z | |
dc.date.available | 2018-03-01T19:50:44Z | |
dc.date.issued | 2006 | |
dc.identifier.issn | 0108-2701 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/3037 | |
dc.description.abstract | The title compound, [Ni(C28H30N3O2PS)], crystallizes with two independent molecules in the asymmetric unit. The Ni-II atoms are in significantly deformed square-planar environments formed by an ONNP donor set from a thiosemicarbazide-based tetradentate ligand. The Ni-II atom and the ONN donor atoms are nearly coplanar, while the P atom deviates from their mean planes by 0.278 (4) and 0.202 (4) angstrom for the two independent molecules. The P-containing chelate rings are remarkably non-planar, adopting a boat conformation, which is unusual for chelate rings in transition metal complexes with thiosemicarbazide-based tetradentate ligands. The orientation of the ethoxy group bonded to this chelate ring is caused by an intramolecular C-H center dot center dot center dot pi interaction with the opposing phenyl ring. There are no hydrogen bonds; instead, numerous intermolecular C-H center dot center dot center dot pi interactions dominate in the crystal packing. | en |
dc.rights | restrictedAccess | en |
dc.source | Acta Crystallographica. Section C: Crystal Structure Communications | en |
dc.title | Transition metal complexes with thiosemicarbazide-based ligands. LIII. [4-(2-diphenylphosphino-alpha-ethoxybenzyl-kappa P)-S-methyl-1-(4-oxidopent-3-en-4-ylidene-kappa O)-thiosemicarbazido-kappa(2) N-1, N-4]nickel (II) | en |
dc.type | article | en |
dcterms.abstract | Драсковиц, Бојана М.; Леовац, Вукадин М.; Полети, Дејан; Богдановић Горан; Брцески, Илија Д.; | |
dc.citation.volume | 62 | |
dc.citation.spage | M319 | |
dc.citation.epage | M322 | |
dc.identifier.wos | 000238803100019 | |
dc.identifier.doi | 10.1107/S0108271016018932 | |
dc.citation.other | Part number: 7 | |
dc.citation.rank | M23 | |
dc.identifier.pmid | 16823202 |
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