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Mesoscopic phase separation in NaxCoO2 (0.65 LT = x LT = 0.75)
dc.creator | Carretta, P | |
dc.creator | Mariani, M | |
dc.creator | Azzoni, CB | |
dc.creator | Mozzati, MC | |
dc.creator | Bradarić, Ivica | |
dc.creator | Savić, Ilija | |
dc.creator | Feher, A | |
dc.creator | Sebek, J | |
dc.date.accessioned | 2018-03-01T19:29:58Z | |
dc.date.available | 2018-03-01T19:29:58Z | |
dc.date.issued | 2004 | |
dc.identifier.issn | 1098-0121 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/2793 | |
dc.description.abstract | Nuclear magnetic resonace (NMR), EPR and magnetization measurements in NaxCoO2 for 0.65less than or equal toxless than or equal to0.75 are presented. While the EPR signal arises from Co4+ magnetic moments ordering at T(c)similar or equal to26 K, Co-59 NMR signal originates from cobalt nuclei in metallic regions with no long range magnetic order and characterized by a generalized susceptibility typical of strongly correlated metallic systems. This phase separation in metallic and magnetic insulating regions is argued to occur below T-*(x) (220-270 K). Above T-* an anomalous decrease in the intensity of the EPR signal is observed and associated with the delocalization of the electrons which for T LT T-* were localized on Co4+ d(z)(2) orbitals. It is pointed out that the in-plane antiferromagnetic coupling JT(*) cannot be the driving force for the phase separation. | en |
dc.rights | restrictedAccess | en |
dc.source | Physical Review B: Condensed Matter and Materials Physics | en |
dc.title | Mesoscopic phase separation in NaxCoO2 (0.65 LT = x LT = 0.75) | en |
dc.type | article | en |
dcterms.abstract | Царретта, П; Мариани, М; Aззони, ЦБ; Савиц, И; Фехер, A; Себек, Ј; Моззати, МЦ; Брадарић Ивица; | |
dc.citation.volume | 70 | |
dc.citation.issue | 2 | |
dc.identifier.wos | 000222996600042 | |
dc.identifier.doi | 10.1103/PhysRevB.70.024409 | |
dc.citation.other | Article Number: 024409 | |
dc.citation.rank | M21 | |
dc.identifier.scopus | 2-s2.0-42749101176 |
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