Methyl methacrylate and acrylamide crosslinked macroporous copolymers
Нема приказа
Аутори
Nikolić, Lj.Skala, Dejan
Nikolić, Vladimir M.
Stamenkovic, J
Babić, Dragan
Ilic-Stojanovic, S
Чланак у часопису
Метаподаци
Приказ свих података о документуАпстракт
In this work the synthesis of a crosslinked macroporous copolymer was effected from methyl methacrylate and acrylamide. The synthesis process began with emulsion prepolymerization, followed by sol-gel copolymerization until a hard block was obtained. Determination of the properties of the obtained material was carried out by FTIR, mercury porosimetry, and SEM microscopy. The material was characterized by a porous structure with open pores. The macroporous copolymer obtained can be used for polymer-analog reactions and the transformation of amide and ester groups into acyl azide groups. It can be used as a hard inert support for the immobilization of enzymes, or other proteins, by condensation of acyl azide group on poly-mer with the free amino group from the base amino acid of enzyme/protein. For the immobilization of microorganisms it can be used by vacuum diffusion of microorganism suspension into the porous structure, without active group transformation reactions. With microorganism...s in the polymer pores, microorganism colonies form within the copolymer by microbial fermentation. (C) 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 387-395, 2004.
Кључне речи:
macroporous polymers / emulsion polymerization / crosslinking / carrier microorganism / enzyme immobilizationИзвор:
Journal of Applied Polymer Science, 2004, 91, 1, 387-395
DOI: 10.1002/app.13113
ISSN: 0021-8995
WoS: 000186915100054
Scopus: 2-s2.0-0348146298
Колекције
Институција/група
VinčaTY - JOUR AU - Nikolić, Lj. AU - Skala, Dejan AU - Nikolić, Vladimir M. AU - Stamenkovic, J AU - Babić, Dragan AU - Ilic-Stojanovic, S PY - 2004 UR - https://vinar.vin.bg.ac.rs/handle/123456789/2690 AB - In this work the synthesis of a crosslinked macroporous copolymer was effected from methyl methacrylate and acrylamide. The synthesis process began with emulsion prepolymerization, followed by sol-gel copolymerization until a hard block was obtained. Determination of the properties of the obtained material was carried out by FTIR, mercury porosimetry, and SEM microscopy. The material was characterized by a porous structure with open pores. The macroporous copolymer obtained can be used for polymer-analog reactions and the transformation of amide and ester groups into acyl azide groups. It can be used as a hard inert support for the immobilization of enzymes, or other proteins, by condensation of acyl azide group on poly-mer with the free amino group from the base amino acid of enzyme/protein. For the immobilization of microorganisms it can be used by vacuum diffusion of microorganism suspension into the porous structure, without active group transformation reactions. With microorganisms in the polymer pores, microorganism colonies form within the copolymer by microbial fermentation. (C) 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 387-395, 2004. T2 - Journal of Applied Polymer Science T1 - Methyl methacrylate and acrylamide crosslinked macroporous copolymers VL - 91 IS - 1 SP - 387 EP - 395 DO - 10.1002/app.13113 ER -
@article{ author = "Nikolić, Lj. and Skala, Dejan and Nikolić, Vladimir M. and Stamenkovic, J and Babić, Dragan and Ilic-Stojanovic, S", year = "2004", abstract = "In this work the synthesis of a crosslinked macroporous copolymer was effected from methyl methacrylate and acrylamide. The synthesis process began with emulsion prepolymerization, followed by sol-gel copolymerization until a hard block was obtained. Determination of the properties of the obtained material was carried out by FTIR, mercury porosimetry, and SEM microscopy. The material was characterized by a porous structure with open pores. The macroporous copolymer obtained can be used for polymer-analog reactions and the transformation of amide and ester groups into acyl azide groups. It can be used as a hard inert support for the immobilization of enzymes, or other proteins, by condensation of acyl azide group on poly-mer with the free amino group from the base amino acid of enzyme/protein. For the immobilization of microorganisms it can be used by vacuum diffusion of microorganism suspension into the porous structure, without active group transformation reactions. With microorganisms in the polymer pores, microorganism colonies form within the copolymer by microbial fermentation. (C) 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 387-395, 2004.", journal = "Journal of Applied Polymer Science", title = "Methyl methacrylate and acrylamide crosslinked macroporous copolymers", volume = "91", number = "1", pages = "387-395", doi = "10.1002/app.13113" }
Nikolić, Lj., Skala, D., Nikolić, V. M., Stamenkovic, J., Babić, D.,& Ilic-Stojanovic, S.. (2004). Methyl methacrylate and acrylamide crosslinked macroporous copolymers. in Journal of Applied Polymer Science, 91(1), 387-395. https://doi.org/10.1002/app.13113
Nikolić L, Skala D, Nikolić VM, Stamenkovic J, Babić D, Ilic-Stojanovic S. Methyl methacrylate and acrylamide crosslinked macroporous copolymers. in Journal of Applied Polymer Science. 2004;91(1):387-395. doi:10.1002/app.13113 .
Nikolić, Lj., Skala, Dejan, Nikolić, Vladimir M., Stamenkovic, J, Babić, Dragan, Ilic-Stojanovic, S, "Methyl methacrylate and acrylamide crosslinked macroporous copolymers" in Journal of Applied Polymer Science, 91, no. 1 (2004):387-395, https://doi.org/10.1002/app.13113 . .