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Magnetic and Mossbauer studies of CaRu(1-)xM(x)O(3) (M = Ti and Fe)
dc.creator | Felner, I | |
dc.creator | Asaf, U | |
dc.creator | Nowik, I | |
dc.creator | Bradarić, Ivica | |
dc.date.accessioned | 2018-03-01T19:08:31Z | |
dc.date.available | 2018-03-01T19:08:31Z | |
dc.date.issued | 2002 | |
dc.identifier.issn | 2469-9950 | |
dc.identifier.issn | 2469-9969 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/2545 | |
dc.description.abstract | CaRuO3 is a perovskite with an orthorhombic distortion and shows the characteristics of spin-glass behavior below T-C=87 K. Magnetic studies of polycrystalline CaRu1-xTixO3 (0 LT x LT 0.1) reveal that a ferromagnetic transition at T-C=34 K appears regardless of the nonmagnetic Ti concentration. On the other hand, magnetic and Mossbauer effect studies show that T-C of CaRu1-xFexO3 (up to x=0.15) is similar to that of pure CaRuO3: however, the Fe induces a ferromagnetic structure. Charge compensation, which is assumed to be present upon Fe3+ substitution, induces the appearance of low-spin Ru5+ ions, which reduce the paramagnetic moment. Huge magnetic hysteresis loops are observed at 5 K, with coercive fields up to 30 kOe. A second magnetic transition around 250 K is observed for Fe concentrations of x=0.25 and 0.35, which is probably caused by Fe-rich clusters. This behavior is consistent with inhomogeneous ferromagnetism found in other perovskite systems. | en |
dc.rights | restrictedAccess | en |
dc.source | Physical Review B: Condensed Matter and Materials Physics | en |
dc.title | Magnetic and Mossbauer studies of CaRu(1-)xM(x)O(3) (M = Ti and Fe) | en |
dc.type | article | en |
dcterms.abstract | Фелнер, И; Aсаф, У; Ноwик, И; Брадарић Ивица; | |
dc.citation.volume | 66 | |
dc.citation.issue | 5 | |
dc.identifier.wos | 000177873000083 | |
dc.identifier.doi | 10.1103/PhysRevB.66.054418 | |
dc.citation.other | Article Number: 054418 | |
dc.identifier.scopus | 2-s2.0-85038929667 |
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