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Thermodynamics of lead(II) halide complex formation in calcium nitrate tetrahydrate - Acetamide melts

dc.creatorGadžurić, Slobodan
dc.creatorZsigrai, Istvan J.
dc.creatorNikolic, RM
dc.date.accessioned2018-03-01T19:04:23Z
dc.date.available2018-03-01T19:04:23Z
dc.date.issued2001
dc.identifier.issn0932-0784
dc.identifier.urihttps://vinar.vin.bg.ac.rs/handle/123456789/2498
dc.description.abstractThe complex formation between lead(II) ions and chloride and bromide ions in melts of Ca(NO3)(2 .) 4H(2)O . aCH(3)CONH(2) has been studied at different temperatures between 30 and 70 C. The formation constants of the complexes PbX+ and PbX2 (X = Cl, Br) were determined from emf measurements by means of Ag/AgX electrodes. The dependence of the formation constants for PbCl+ on the solvent melt composition has been analysed. The thermodynamic parameters DeltaH(11)(0) and DeltaS(11)(0) for PbX+ complex formation have been estimated. The parameters are compared with the literature data for the same process in dilute aqueous solutions and in some hydrated and anhydrous salt melts.en
dc.rightsrestrictedAccessen
dc.sourceZeitschrift fur Naturforschung. Section A: Journal of Physical Sciencesen
dc.subjectlead(II) halide complexesen
dc.subjectacetamideen
dc.subjectcalcium nitrate tetrahydrateen
dc.titleThermodynamics of lead(II) halide complex formation in calcium nitrate tetrahydrate - Acetamide meltsen
dc.typearticleen
dcterms.abstractЗсиграи, ИЈ; Николиц, РМ; Гадзуриц, СБ;
dc.citation.volume56
dc.citation.issue12
dc.citation.spage832
dc.citation.epage836
dc.identifier.wos000173807200006
dc.citation.rankM23
dc.identifier.rcubhttps://hdl.handle.net/21.15107/rcub_vinar_2498


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