Some problems connected with boron determination by atomic absorption spectroscopy and the sensitivity improvement
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Two atomizers were compared: an N2O-C2H2 flame and a stabilized U-shaped DC arc with aerosol supply. Both the high plasma temperature and the reducing atmosphere obtained by acetylene addition to the argon stream substantially increase the sensitivity of boron determination by atomic absorption spectroscopy (AAS) when the arc atomizer is used. The results were compared with those for silicon as a control element. The experimental characteristic concentrations for both elements were compared with the computed values. The experimentally obtained characteristic concentration for boron when using the arc atomizer was in better agreement with the calculated value. It was estimated that the influence of stable monoxide formation on the sensitivity for both elements was about the same, but reduction of analyte and formation of non-volatile carbide particles was more important for boron, which is the main reason for the low sensitivity of boron determination using a flame atomizer. The use of ...an arc atomizer suppresses this interference and significantly improves the sensitivity of the determination.
Кључне речи:boron / atomic absorption spectroscopy / characteristic concentration / DC arc plasma
Извор:Journal of the Serbian Chemical Society, 2001, 66, 8, 535-542
ISSN: 0352-5139 (print)