Transition metal complexes with pyrazole-derived ligands. XI. [Zn(mu-L)(HL)(OAc)](2) (HL is 4-acetyl-3-amino-5-methylpyrazole)
Апстракт
The title compound, bis(mu-4-acetyl-3-amino-5-methylpyrazolato-N-1 :N-2)bis[(acetato-O)(4-acetyl-3-amino-5-methylpyrazole-N-2)zinc(II)], [Zn-2(C6H8N3O)(2)(C2H3O2)(2)(C6H9N3O)(2)], exists as a centrosymmetric binuclear molecule with two tetrahedrally coordinated Zn atoms bridged by two pyrazolate anions. The geometry of the terminal and bridging pyrazole ligands are slightly different as a consequence of their differing modes of coordination.
Извор:
Acta Crystallographica. Section C: Crystal Structure Communications, 2000, 56, 777-779
DOI: 10.1107/S0108270100004881
ISSN: 0108-2701
WoS: 000088144900017
Scopus: 2-s2.0-0343826090
Колекције
Институција/група
VinčaTY - JOUR AU - Tomić, Zoran D. AU - Jacimovic, ZK AU - Leovac, Vukadin M. AU - Češljević, Valerija I. PY - 2000 UR - https://vinar.vin.bg.ac.rs/handle/123456789/2360 AB - The title compound, bis(mu-4-acetyl-3-amino-5-methylpyrazolato-N-1 :N-2)bis[(acetato-O)(4-acetyl-3-amino-5-methylpyrazole-N-2)zinc(II)], [Zn-2(C6H8N3O)(2)(C2H3O2)(2)(C6H9N3O)(2)], exists as a centrosymmetric binuclear molecule with two tetrahedrally coordinated Zn atoms bridged by two pyrazolate anions. The geometry of the terminal and bridging pyrazole ligands are slightly different as a consequence of their differing modes of coordination. T2 - Acta Crystallographica. Section C: Crystal Structure Communications T1 - Transition metal complexes with pyrazole-derived ligands. XI. [Zn(mu-L)(HL)(OAc)](2) (HL is 4-acetyl-3-amino-5-methylpyrazole) VL - 56 SP - 777 EP - 779 DO - 10.1107/S0108270100004881 ER -
@article{ author = "Tomić, Zoran D. and Jacimovic, ZK and Leovac, Vukadin M. and Češljević, Valerija I.", year = "2000", abstract = "The title compound, bis(mu-4-acetyl-3-amino-5-methylpyrazolato-N-1 :N-2)bis[(acetato-O)(4-acetyl-3-amino-5-methylpyrazole-N-2)zinc(II)], [Zn-2(C6H8N3O)(2)(C2H3O2)(2)(C6H9N3O)(2)], exists as a centrosymmetric binuclear molecule with two tetrahedrally coordinated Zn atoms bridged by two pyrazolate anions. The geometry of the terminal and bridging pyrazole ligands are slightly different as a consequence of their differing modes of coordination.", journal = "Acta Crystallographica. Section C: Crystal Structure Communications", title = "Transition metal complexes with pyrazole-derived ligands. XI. [Zn(mu-L)(HL)(OAc)](2) (HL is 4-acetyl-3-amino-5-methylpyrazole)", volume = "56", pages = "777-779", doi = "10.1107/S0108270100004881" }
Tomić, Z. D., Jacimovic, Z., Leovac, V. M.,& Češljević, V. I.. (2000). Transition metal complexes with pyrazole-derived ligands. XI. [Zn(mu-L)(HL)(OAc)](2) (HL is 4-acetyl-3-amino-5-methylpyrazole). in Acta Crystallographica. Section C: Crystal Structure Communications, 56, 777-779. https://doi.org/10.1107/S0108270100004881
Tomić ZD, Jacimovic Z, Leovac VM, Češljević VI. Transition metal complexes with pyrazole-derived ligands. XI. [Zn(mu-L)(HL)(OAc)](2) (HL is 4-acetyl-3-amino-5-methylpyrazole). in Acta Crystallographica. Section C: Crystal Structure Communications. 2000;56:777-779. doi:10.1107/S0108270100004881 .
Tomić, Zoran D., Jacimovic, ZK, Leovac, Vukadin M., Češljević, Valerija I., "Transition metal complexes with pyrazole-derived ligands. XI. [Zn(mu-L)(HL)(OAc)](2) (HL is 4-acetyl-3-amino-5-methylpyrazole)" in Acta Crystallographica. Section C: Crystal Structure Communications, 56 (2000):777-779, https://doi.org/10.1107/S0108270100004881 . .