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Microcalorimetric studies of electrolyte mixtures: HCl-GaCl3 - Application of Pitzers model

dc.creatorMarković, Mirjana
dc.creatorMilonjić, Slobodan K.
dc.date.accessioned2018-03-01T18:51:07Z
dc.date.available2018-03-01T18:51:07Z
dc.date.issued2000
dc.identifier.issn0040-6031
dc.identifier.urihttps://vinar.vin.bg.ac.rs/handle/123456789/2346
dc.description.abstractThe heat of mixing of HCl and GaCl3 concentrated isomolal aqueous solutions has been measured, in the 0.0005-0.159 molality and 293-333 K temperature range by a flow-mix microcalorimetric method, to determine the thermodynamic properties of the solutions. The results obtained have been successfully explained by Fitters ion interaction model. Fitters mixing coefficients have been calculated and used to study the nature and intensity of ion interactions in the mixed solutions. Using Fitters parameters, the activity coefficients of the mixture components have been calculated. (C) 2000 Elsevier Science B.V. All rights reserved.en
dc.rightsrestrictedAccessen
dc.sourceThermochimica Actaen
dc.subjectheat of mixingen
dc.subjectmicrocalorimetryen
dc.subjectelectrolytesen
dc.subjectthermodynamics of mixingen
dc.subjectPitzers modelen
dc.titleMicrocalorimetric studies of electrolyte mixtures: HCl-GaCl3 - Application of Pitzers modelen
dc.typearticleen
dcterms.abstractМарковић Мирјана; Милоњић Слободан;
dc.citation.volume351
dc.citation.issue1-2
dc.citation.spage153
dc.citation.epage157
dc.identifier.wos000087255800021
dc.identifier.doi10.1016/S0040-6031(00)00434-2
dc.citation.rankM23
dc.identifier.scopus2-s2.0-0034209389


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