Transition metal complexes with thiosemicarbazide-based ligands. XXXIX. [Benzoylacetone 3-methylisothiosemicarbazonato(2)-O,N-1,N-4](pyridine-N)nickel(II)
Апстракт
The square-planar title complex of formula [Ni(C12H13N3OS)(C6H5N)] or [Ni(L)(py)] (L is the dianion of the O,N,N-terdentate benzoylacetone S-methylisothio-semicarbazone ligand and py is pyridine) has structural characteristics of the ligand L somewhat different from those reported previously for the square-planar [Ni(HL)(NH3)]I complex, which involves the same ligand in its monoanionic form. The differences are in the different electronic delocalization in the isothiosemicarbazide moiety, and the trans orientation of the S-Me group and the imido N atom. The effect of H-atom repulsion on the orientation of the phenyl ring with respect to the coordination plane of the complex and the effect of the pyridine ring on the crystal packing are also described.
Извор:
Acta Crystallographica. Section C: Crystal Structure Communications, 1999, 55, 1656-1658
DOI: 10.1107/S0108270199004746
ISSN: 0108-2701
WoS: 000083575100019
Scopus: 2-s2.0-0001136592
Колекције
Институција/група
VinčaTY - JOUR AU - Bogdanović, Goran A. AU - Spasojević-de Bire, Anne AU - Leovac, Vukadin M. AU - Češljević, Valerija I. PY - 1999 UR - https://vinar.vin.bg.ac.rs/handle/123456789/2289 AB - The square-planar title complex of formula [Ni(C12H13N3OS)(C6H5N)] or [Ni(L)(py)] (L is the dianion of the O,N,N-terdentate benzoylacetone S-methylisothio-semicarbazone ligand and py is pyridine) has structural characteristics of the ligand L somewhat different from those reported previously for the square-planar [Ni(HL)(NH3)]I complex, which involves the same ligand in its monoanionic form. The differences are in the different electronic delocalization in the isothiosemicarbazide moiety, and the trans orientation of the S-Me group and the imido N atom. The effect of H-atom repulsion on the orientation of the phenyl ring with respect to the coordination plane of the complex and the effect of the pyridine ring on the crystal packing are also described. T2 - Acta Crystallographica. Section C: Crystal Structure Communications T1 - Transition metal complexes with thiosemicarbazide-based ligands. XXXIX. [Benzoylacetone 3-methylisothiosemicarbazonato(2)-O,N-1,N-4](pyridine-N)nickel(II) VL - 55 SP - 1656 EP - 1658 DO - 10.1107/S0108270199004746 ER -
@article{ author = "Bogdanović, Goran A. and Spasojević-de Bire, Anne and Leovac, Vukadin M. and Češljević, Valerija I.", year = "1999", abstract = "The square-planar title complex of formula [Ni(C12H13N3OS)(C6H5N)] or [Ni(L)(py)] (L is the dianion of the O,N,N-terdentate benzoylacetone S-methylisothio-semicarbazone ligand and py is pyridine) has structural characteristics of the ligand L somewhat different from those reported previously for the square-planar [Ni(HL)(NH3)]I complex, which involves the same ligand in its monoanionic form. The differences are in the different electronic delocalization in the isothiosemicarbazide moiety, and the trans orientation of the S-Me group and the imido N atom. The effect of H-atom repulsion on the orientation of the phenyl ring with respect to the coordination plane of the complex and the effect of the pyridine ring on the crystal packing are also described.", journal = "Acta Crystallographica. Section C: Crystal Structure Communications", title = "Transition metal complexes with thiosemicarbazide-based ligands. XXXIX. [Benzoylacetone 3-methylisothiosemicarbazonato(2)-O,N-1,N-4](pyridine-N)nickel(II)", volume = "55", pages = "1656-1658", doi = "10.1107/S0108270199004746" }
Bogdanović, G. A., Spasojević-de Bire, A., Leovac, V. M.,& Češljević, V. I.. (1999). Transition metal complexes with thiosemicarbazide-based ligands. XXXIX. [Benzoylacetone 3-methylisothiosemicarbazonato(2)-O,N-1,N-4](pyridine-N)nickel(II). in Acta Crystallographica. Section C: Crystal Structure Communications, 55, 1656-1658. https://doi.org/10.1107/S0108270199004746
Bogdanović GA, Spasojević-de Bire A, Leovac VM, Češljević VI. Transition metal complexes with thiosemicarbazide-based ligands. XXXIX. [Benzoylacetone 3-methylisothiosemicarbazonato(2)-O,N-1,N-4](pyridine-N)nickel(II). in Acta Crystallographica. Section C: Crystal Structure Communications. 1999;55:1656-1658. doi:10.1107/S0108270199004746 .
Bogdanović, Goran A., Spasojević-de Bire, Anne, Leovac, Vukadin M., Češljević, Valerija I., "Transition metal complexes with thiosemicarbazide-based ligands. XXXIX. [Benzoylacetone 3-methylisothiosemicarbazonato(2)-O,N-1,N-4](pyridine-N)nickel(II)" in Acta Crystallographica. Section C: Crystal Structure Communications, 55 (1999):1656-1658, https://doi.org/10.1107/S0108270199004746 . .