Energetics of the ionization and fragmentation of sulfur-containing molecules studied by electron-impact spectroscopy. I. SO2F2
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The positive ions produced by the dissociative ionization on SO2F2 were studied using a trochoidal electron monochromator as an electron Sun. The appearance energies of the fragment ions were measured and interpreted in terms of possible fragmentation mechanisms. The results were used to determine the ionization energies and heats of formation of the observed fragment species.