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Spectrophotometric study of hexanitrocobaltate(III) ion spontaneous reduction in water-ethanol and water-acetone mixtures
dc.creator | Sovilj, Sofija P. | |
dc.creator | Vasić, Vesna M. | |
dc.creator | Stojić, Dragica Lj. | |
dc.date.accessioned | 2018-03-01T18:30:33Z | |
dc.date.available | 2018-03-01T18:30:33Z | |
dc.date.issued | 1998 | |
dc.identifier.issn | 0038-7010 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/2113 | |
dc.description.abstract | The kinetics of the spontaneous reduction of hexanitrocobaltate(III) ion have been investigated spectrophotometrically (lambda=360 nm at 298 K) in ethanol or acetone water mixtures containing 0, 10, 25 and 50 % of organic solvents. The mechanism of this process was expressed by means of two consecutive first-order reactions. Both of the first-order rate constants decrease with the increasing nonaqueous species content. The reduction of hexanitrocobaltate(III) ion in the mixtures was much slower than the corresponding reaction in water. | en |
dc.rights | restrictedAccess | en |
dc.source | Spectroscopy Letters | en |
dc.subject | hexanitrocobaltate (III) ion | en |
dc.subject | reduction | en |
dc.subject | mixed solvents | en |
dc.subject | kinetics | en |
dc.title | Spectrophotometric study of hexanitrocobaltate(III) ion spontaneous reduction in water-ethanol and water-acetone mixtures | en |
dc.type | article | en |
dc.rights.license | ARR | |
dcterms.abstract | Совиљ, СП; Васић Весна М; Стојиц, ДЛ; | |
dc.citation.volume | 31 | |
dc.citation.issue | 1 | |
dc.citation.spage | 71 | |
dc.citation.epage | 85 | |
dc.identifier.wos | 000072123800007 | |
dc.identifier.doi | 10.1080/00387019808006762 | |
dc.citation.rank | M23 | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-0042723616 |