Show simple item record

dc.creatorPrelesnik, BV
dc.creatorRadanovic, DD
dc.creatorTomić, Zoran D.
dc.creatorDjurdjevic, P
dc.creatorRadanovic, DJ
dc.creatorVeselinovic, DS
dc.date.accessioned2018-03-01T18:14:53Z
dc.date.available2018-03-01T18:14:53Z
dc.date.issued1996
dc.identifier.issn0277-5387 (print)
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/2005
dc.description.abstractThe hexadentate complex [Cu(H(2)1,3-pddadp)]. 1.5H(2)O (1,3-pddadp = 1,3-propanediamine-N,N-diacetate-N,N-di-3-propionate ion) has been prepared and isolated and its molecular structure determined by the single crystal X-ray diffraction technique. The complex is a trans(O-6) isomer, in which the copper(II) ion is surrounded octahedrally by two nitrogen and four oxygen atoms of 1,3-pddadp with two protonated beta-alaninate rings in trans positions. The copper atom environment is a tetragonally elongated octahedron with tetragonality (T) 0.798. A comparison of structures of the copper(II)-edta-type complexes shows an expected variation in their stereochemistry, depending on the structure of the ligand. The 1,3-pddadp ligand encircles the Cu-II ion more favourably than the edta ligand, which is capable of forming five-membered chelate rings only. Some properties of the complex are also given. Copyright (C) 1996 Elsevier Science Ltden
dc.rightsrestrictedAccessen
dc.sourcePolyhedronen
dc.titlePreparation and molecular structure of the trans(O-6) isomer of dihydrogen (1,3-propanediamine-N,N-diacetato-N,N-di-3-propionato)copper(II) complex. The stereochemistry of copper(II)-EDTA-type complexes in relation to the structure of the liganden
dc.typearticleen
dcterms.abstractРадановиц, ДЈ; Радановиц, ДД; Дјурдјевиц, П; Веселиновиц, ДС; Прелесник, БВ; Томић Зоран;
dc.citation.volume15
dc.citation.issue21
dc.citation.spage3761
dc.citation.epage3770
dc.identifier.wosA1996VB67200012
dc.identifier.doi10.1016/0277-5387(96)00115-5
dc.identifier.scopus2-s2.0-0001734982


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record