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dc.creatorDamljanović, Ivan S.
dc.creatorStevanović, Dragana D.
dc.creatorPejović, Anka
dc.creatorIlic, Danijela
dc.creatorŽivković, Marija
dc.creatorJovanović, Jovana P.
dc.creatorVukicevic, Mirjana
dc.creatorBogdanović, Goran A.
dc.creatorRadulovic, Niko S.
dc.creatorVukicevic, Rastko D.
dc.date.accessioned2018-03-01T15:29:56Z
dc.date.available2018-03-01T15:29:56Z
dc.date.issued2014
dc.identifier.issn2046-2069 (print)
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/193
dc.description.abstractIn this paper we wish to present the first results on the synthesis of N, N-diethyl-1-ferrocenyl-3-thiabutanamine, its coordination with palladium(II), the complete characterization of the thus obtained complex (including single crystal X-ray analysis for the complex in two polymorphic forms) and screening of its catalytic activity in Suzuki-Miyaura coupling of phenylboronic acid with several aryl bromides. The complex, either purified and then added to the reaction mixture or generated in situ, proved to be an excellent precatalyst in Suzuki-Miyaura coupling. The chemical behavior of the complex in solution was assessed by detailed NMR analyses and cyclic voltammetry measurements which allowed us to draw a number of mechanistic conclusions.en
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172034/RS//
dc.rightsrestrictedAccessen
dc.sourceRSC Advancesen
dc.titleThe palladium(II) complex of N,N-diethyl-1-ferrocenyl-3-thiabutanamine: synthesis, solution and solid state structure and catalytic activity in Suzuki-Miyaura reactionen
dc.typearticleen
dcterms.abstractДамљановиц, Иван; Радуловиц, Нико С.; Богдановић Горан; Јовановиц, Јована; Илиц, Данијела; Стевановиц, Драгана; Зивковиц, Марија; Пејовиц, Aнка; Вукицевиц, Мирјана; Вукицевиц, Растко Д.;
dc.citation.volume4
dc.citation.issue82
dc.citation.spage43792
dc.citation.epage43799
dc.identifier.wos000344526700067
dc.identifier.doi10.1039/c4ra08140d
dc.citation.rankM21
dc.identifier.scopus2-s2.0-84907833845


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