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Vibrational and electron paramagnetic resonance spectroscopic studies of beta-MnO2 and alpha-KxMnO(2) nanorods
dc.creator | Barudžija, Tanja | |
dc.creator | Cvjetićanin, Nikola | |
dc.creator | Bajuk-Bogdanović, Danica V. | |
dc.creator | Mojovic, Milos | |
dc.creator | Mitrić, Miodrag | |
dc.date.accessioned | 2018-03-01T17:55:13Z | |
dc.date.available | 2018-03-01T17:55:13Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 0925-8388 | |
dc.identifier.issn | 1873-4669 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/1777 | |
dc.description.abstract | Raman scattering (RS), Fourier transform infrared (FTIR) and electron paramagnetic resonance (EPR) spectroscopic measurements on beta-MnO2 and alpha-KxMnO2 nanorods were performed. The infrared spectrum of beta-MnO2 is sensitive towards the particle sizes, while the Raman spectrum is sensitive towards the presence of nonstoichiometric and disordered MnO2-delta on the surface of nanorods. EPR measurements show the appearance of two types of Mn4+ ions having different local environment: (i) Mn4+ ions in Mn4+-rich environment and (ii) Mn4+ ions in mixed-valence Mn4+/Mn3+ environment that match up with region of nonstoichiometric MnO2-delta. Observed bands in vibrational spectra of tetragonal hollanditetype alpha-KxMnO(2) are considered to be mainly due to the vibration modes of Mn-O frameworks. The EPR spectra of alpha-KxMnO(2) nanorods contain two signals that can be attributed to Mn4+ ions in Mn4+-rich environment and Mn4+ ions in mixed-valence Mn4+/Mn3+ environment close to K+ ions. (C) 2017 Elsevier B.V. All rights reserved. | en |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45015/RS// | |
dc.rights | restrictedAccess | en |
dc.source | Journal of Alloys and Compounds | en |
dc.subject | Manganese dioxide materials | en |
dc.subject | Raman scattering spectroscopy | en |
dc.subject | Infrared spectroscopy | en |
dc.subject | Electron paramagnetic resonance | en |
dc.subject | X-ray diffraction | en |
dc.title | Vibrational and electron paramagnetic resonance spectroscopic studies of beta-MnO2 and alpha-KxMnO(2) nanorods | en |
dc.type | article | en |
dc.rights.license | ARR | |
dcterms.abstract | Бајук-Богдановиц, Даница; Баруджија Тања; Цвјетицанин, Никола; Мојовиц, Милос; Митрић Миодраг; | |
dc.citation.volume | 728 | |
dc.citation.spage | 259 | |
dc.citation.epage | 270 | |
dc.identifier.wos | 000412818600029 | |
dc.identifier.doi | 10.1016/j.jallcom.2017.09.015 | |
dc.citation.rank | aM21 | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-85028743086 |