Biodegradation of cotton and cotton/polyester with Ag/TiO2 nanoparticles in soil
Само за регистроване кориснике
2017
Аутори
Milošević, Milica V.Krkobabic, Ana
Radoičić, Marija B.
Šaponjić, Zoran
Radetić, Tamara
Radetić, Maja M.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
This study discusses the biodegradation behavior of cotton and cotton/PET fabrics impregnated with Ag/TiO2 nanoparticles in soil. Biodegradation behavior was evaluated by standard test method ASTM 5988-03 based on determination of percentage conversions of carbon content to CO2 as well as by soil burial test and enzymatic hydrolysis with cellulase where the extent of biodegradation was estimated by the calculation of fabric weight loss. The morphological and chemical changes of fibers during biodegradation process were analyzed by SEM and FTIR spectroscopy, respectively. The results obtained by all applied methods suggested that Ag/TiO2 nanoparticles hindered the biodegradation of investigated cotton and cotton/PET fabrics. Soil burial test indicated faster biodegradation of the impregnated blend compared to impregnated cotton fabric which is attributed to smaller amount of fabricated Ag nanoparticles on the blend proved by MS measurement. Similar trend was established by enzymatic hyd...rolysis of cotton fibers. Severe damage of cotton fibers in both fabrics due to biodegradation process was confirmed by SEM. However, the cotton fiber damage occurred to a lesser extent in the samples that were impregnated with Ag/TiO2 nanoparticles. PET fibers remained intact which was also indicated by FTIR analysis. (C) 2016 Elsevier Ltd. All rights reserved.
Кључне речи:
Cotton / Cotton/PET / Ag/TiO2 nanoparticles / Biodegradation / SoilИзвор:
Carbohydrate Polymers, 2017, 158, 77-84Финансирање / пројекти:
- Материјали редуковане димензионалности за ефикасну апсорпцију светлости и конверзију енергије (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45020)
- Утицај величине, облика и структуре наночестица на њихова својства и својства нанокомпозита (RS-MESTD-Basic Research (BR or ON)-172056)
DOI: 10.1016/j.carbpol.2016.12.006
ISSN: 0144-8617; 1879-1344
PubMed: 28024545
WoS: 000393252500010
Scopus: 2-s2.0-85000932375
Колекције
Институција/група
VinčaTY - JOUR AU - Milošević, Milica V. AU - Krkobabic, Ana AU - Radoičić, Marija B. AU - Šaponjić, Zoran AU - Radetić, Tamara AU - Radetić, Maja M. PY - 2017 UR - https://vinar.vin.bg.ac.rs/handle/123456789/1415 AB - This study discusses the biodegradation behavior of cotton and cotton/PET fabrics impregnated with Ag/TiO2 nanoparticles in soil. Biodegradation behavior was evaluated by standard test method ASTM 5988-03 based on determination of percentage conversions of carbon content to CO2 as well as by soil burial test and enzymatic hydrolysis with cellulase where the extent of biodegradation was estimated by the calculation of fabric weight loss. The morphological and chemical changes of fibers during biodegradation process were analyzed by SEM and FTIR spectroscopy, respectively. The results obtained by all applied methods suggested that Ag/TiO2 nanoparticles hindered the biodegradation of investigated cotton and cotton/PET fabrics. Soil burial test indicated faster biodegradation of the impregnated blend compared to impregnated cotton fabric which is attributed to smaller amount of fabricated Ag nanoparticles on the blend proved by MS measurement. Similar trend was established by enzymatic hydrolysis of cotton fibers. Severe damage of cotton fibers in both fabrics due to biodegradation process was confirmed by SEM. However, the cotton fiber damage occurred to a lesser extent in the samples that were impregnated with Ag/TiO2 nanoparticles. PET fibers remained intact which was also indicated by FTIR analysis. (C) 2016 Elsevier Ltd. All rights reserved. T2 - Carbohydrate Polymers T1 - Biodegradation of cotton and cotton/polyester with Ag/TiO2 nanoparticles in soil VL - 158 SP - 77 EP - 84 DO - 10.1016/j.carbpol.2016.12.006 ER -
@article{ author = "Milošević, Milica V. and Krkobabic, Ana and Radoičić, Marija B. and Šaponjić, Zoran and Radetić, Tamara and Radetić, Maja M.", year = "2017", abstract = "This study discusses the biodegradation behavior of cotton and cotton/PET fabrics impregnated with Ag/TiO2 nanoparticles in soil. Biodegradation behavior was evaluated by standard test method ASTM 5988-03 based on determination of percentage conversions of carbon content to CO2 as well as by soil burial test and enzymatic hydrolysis with cellulase where the extent of biodegradation was estimated by the calculation of fabric weight loss. The morphological and chemical changes of fibers during biodegradation process were analyzed by SEM and FTIR spectroscopy, respectively. The results obtained by all applied methods suggested that Ag/TiO2 nanoparticles hindered the biodegradation of investigated cotton and cotton/PET fabrics. Soil burial test indicated faster biodegradation of the impregnated blend compared to impregnated cotton fabric which is attributed to smaller amount of fabricated Ag nanoparticles on the blend proved by MS measurement. Similar trend was established by enzymatic hydrolysis of cotton fibers. Severe damage of cotton fibers in both fabrics due to biodegradation process was confirmed by SEM. However, the cotton fiber damage occurred to a lesser extent in the samples that were impregnated with Ag/TiO2 nanoparticles. PET fibers remained intact which was also indicated by FTIR analysis. (C) 2016 Elsevier Ltd. All rights reserved.", journal = "Carbohydrate Polymers", title = "Biodegradation of cotton and cotton/polyester with Ag/TiO2 nanoparticles in soil", volume = "158", pages = "77-84", doi = "10.1016/j.carbpol.2016.12.006" }
Milošević, M. V., Krkobabic, A., Radoičić, M. B., Šaponjić, Z., Radetić, T.,& Radetić, M. M.. (2017). Biodegradation of cotton and cotton/polyester with Ag/TiO2 nanoparticles in soil. in Carbohydrate Polymers, 158, 77-84. https://doi.org/10.1016/j.carbpol.2016.12.006
Milošević MV, Krkobabic A, Radoičić MB, Šaponjić Z, Radetić T, Radetić MM. Biodegradation of cotton and cotton/polyester with Ag/TiO2 nanoparticles in soil. in Carbohydrate Polymers. 2017;158:77-84. doi:10.1016/j.carbpol.2016.12.006 .
Milošević, Milica V., Krkobabic, Ana, Radoičić, Marija B., Šaponjić, Zoran, Radetić, Tamara, Radetić, Maja M., "Biodegradation of cotton and cotton/polyester with Ag/TiO2 nanoparticles in soil" in Carbohydrate Polymers, 158 (2017):77-84, https://doi.org/10.1016/j.carbpol.2016.12.006 . .