In-situ desorption of magnesium hydride irradiated and non-irradiated thin films: Relation to optical properties
Samo za registrovane korisnike
2017
Autori
Rašković-Lovre, ŽeljkaKurko, Sandra V.
Ivanović, Nenad
Fernandez, Jose Francisco
Ares, Jose-Ramon
Sturm, Saso
Mongstad, Trygve
Novaković, Nikola
Grbović-Novaković, Jasmina
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Processes taking place during hydrogen desorption from MgH2 thin films were investigated in as-prepared samples and samples modified by argon ion irradiation. Irradiation was used to produce well-defined defects with depth distribution. It was shown that the size, shape, and concentration of Mg nuclei formed during hydrogen desorption from MgH2 thin films depend on the characteristics and distribution of the induced defects. In as-prepared samples the shape of Mg nuclei is spherical, while in irradiated samples, it is highly irregular. Variations in sample colour were observed during hydrogen desorption and before the creation of Mg nuclei. DFT calculations showed that the observed variations in the optical properties of samples can be explained by changes in MgH2 electronic structure -the appearance of an H-vacancy band within the MgH2 energy gap. (C) 2016 Elsevier B.V. All rights reserved.
Ključne reči:
Metallic hydrides / Thin films / Hydrogen desorption behaviour / Optical properties / DFTIzvor:
Journal of Alloys and Compounds, 2017, 695, 2381-2388Finansiranje / projekti:
- ESTEEM 2 - Enabling Science and Technology through European Electron Microscopy (EU-FP7-312483)
- Sinteza, procesiranje i karakterizacija nanostrukturnih materijala za primenu u oblasti energije, mehaničkog inženjerstva, zaštite životne stredine i biomedicine (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45012)
DOI: 10.1016/j.jallcom.2016.11.128
ISSN: 0925-8388; 1873-4669
WoS: 000391817600300
Scopus: 2-s2.0-85006957105
Kolekcije
Institucija/grupa
VinčaTY - JOUR AU - Rašković-Lovre, Željka AU - Kurko, Sandra V. AU - Ivanović, Nenad AU - Fernandez, Jose Francisco AU - Ares, Jose-Ramon AU - Sturm, Saso AU - Mongstad, Trygve AU - Novaković, Nikola AU - Grbović-Novaković, Jasmina PY - 2017 UR - https://vinar.vin.bg.ac.rs/handle/123456789/1381 AB - Processes taking place during hydrogen desorption from MgH2 thin films were investigated in as-prepared samples and samples modified by argon ion irradiation. Irradiation was used to produce well-defined defects with depth distribution. It was shown that the size, shape, and concentration of Mg nuclei formed during hydrogen desorption from MgH2 thin films depend on the characteristics and distribution of the induced defects. In as-prepared samples the shape of Mg nuclei is spherical, while in irradiated samples, it is highly irregular. Variations in sample colour were observed during hydrogen desorption and before the creation of Mg nuclei. DFT calculations showed that the observed variations in the optical properties of samples can be explained by changes in MgH2 electronic structure -the appearance of an H-vacancy band within the MgH2 energy gap. (C) 2016 Elsevier B.V. All rights reserved. T2 - Journal of Alloys and Compounds T1 - In-situ desorption of magnesium hydride irradiated and non-irradiated thin films: Relation to optical properties VL - 695 SP - 2381 EP - 2388 DO - 10.1016/j.jallcom.2016.11.128 ER -
@article{ author = "Rašković-Lovre, Željka and Kurko, Sandra V. and Ivanović, Nenad and Fernandez, Jose Francisco and Ares, Jose-Ramon and Sturm, Saso and Mongstad, Trygve and Novaković, Nikola and Grbović-Novaković, Jasmina", year = "2017", abstract = "Processes taking place during hydrogen desorption from MgH2 thin films were investigated in as-prepared samples and samples modified by argon ion irradiation. Irradiation was used to produce well-defined defects with depth distribution. It was shown that the size, shape, and concentration of Mg nuclei formed during hydrogen desorption from MgH2 thin films depend on the characteristics and distribution of the induced defects. In as-prepared samples the shape of Mg nuclei is spherical, while in irradiated samples, it is highly irregular. Variations in sample colour were observed during hydrogen desorption and before the creation of Mg nuclei. DFT calculations showed that the observed variations in the optical properties of samples can be explained by changes in MgH2 electronic structure -the appearance of an H-vacancy band within the MgH2 energy gap. (C) 2016 Elsevier B.V. All rights reserved.", journal = "Journal of Alloys and Compounds", title = "In-situ desorption of magnesium hydride irradiated and non-irradiated thin films: Relation to optical properties", volume = "695", pages = "2381-2388", doi = "10.1016/j.jallcom.2016.11.128" }
Rašković-Lovre, Ž., Kurko, S. V., Ivanović, N., Fernandez, J. F., Ares, J., Sturm, S., Mongstad, T., Novaković, N.,& Grbović-Novaković, J.. (2017). In-situ desorption of magnesium hydride irradiated and non-irradiated thin films: Relation to optical properties. in Journal of Alloys and Compounds, 695, 2381-2388. https://doi.org/10.1016/j.jallcom.2016.11.128
Rašković-Lovre Ž, Kurko SV, Ivanović N, Fernandez JF, Ares J, Sturm S, Mongstad T, Novaković N, Grbović-Novaković J. In-situ desorption of magnesium hydride irradiated and non-irradiated thin films: Relation to optical properties. in Journal of Alloys and Compounds. 2017;695:2381-2388. doi:10.1016/j.jallcom.2016.11.128 .
Rašković-Lovre, Željka, Kurko, Sandra V., Ivanović, Nenad, Fernandez, Jose Francisco, Ares, Jose-Ramon, Sturm, Saso, Mongstad, Trygve, Novaković, Nikola, Grbović-Novaković, Jasmina, "In-situ desorption of magnesium hydride irradiated and non-irradiated thin films: Relation to optical properties" in Journal of Alloys and Compounds, 695 (2017):2381-2388, https://doi.org/10.1016/j.jallcom.2016.11.128 . .