Influence of the synthesis parameters on the properties of the sepiolite-based magnetic adsorbents
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2017
Authors
Ahribesh, Aysha AliLazarevic, Slavica
Jankovic-Častvan, Ivona
Jokić, Bojan M.
Spasojević, Vojislav
Radetić, Tamara
Janaćković, Đorđe T.
Petrović, Rada
Article (Published version)
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© 2016 Elsevier B.V.
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The magnetic nanocomposites (MNCs), used as adsorbents for Cd2+ ions, were prepared by a co-precipitation method using both the untreated natural (SEP) and the partially acid-activated (ASEP) sepiolites as supports for magnetite. The synthesis conditions differed as follows: NaOH or NH3 was added in the SEP or the ASEP suspension before or after the addition of Fe3 and Fe2+. The SEP-based MNCs prepared using NaOH had a lower magnetization, but higher adsorption capacities than the MNCs synthesized using NH3. The order of the mixing of the reagents had a small influence on the properties of SEP-based MNCs, especially when NaOH was used for the synthesis. Due to acidity of the surface functional groups of the ASEP, the magnetic composite could be synthesized only when NH3 was added in the suspension of ASEP having Fe3+ and Fe2+ ions. Despite of the worse dispersibility of the magnetic particles, the adsorption capacityof the ASEP-based composite was higher than of the MNC with SEP prepar...ed by the same procedure. All the MNCs showed a superparamagnetic behavior at room temperature and the adsorption capacities were higher than of pure compounds. The adsorption of Cd2+ on the composites was best fitted with the Sips model, which suggested the chemisorption on the heterogeneous surface at energetically non-uniform sites until a monolayer was formed. (C) 2016 Elsevier B.V. All rights reserved.
Keywords:
Magnetic nanocomposites / Sepiolite/acid-activated sepiolite / Co-precipitation, synthesis parameters / Cd2+ adsorptionSource:
Powder Technology, 2017, 305, 260-269Funding / projects:
- Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45019)
DOI: 10.1016/j.powtec.2016.09.086
ISSN: 0032-5910; 1873-328X
WoS: 000390732000030
Scopus: 2-s2.0-84991087342
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VinčaTY - JOUR AU - Ahribesh, Aysha Ali AU - Lazarevic, Slavica AU - Jankovic-Častvan, Ivona AU - Jokić, Bojan M. AU - Spasojević, Vojislav AU - Radetić, Tamara AU - Janaćković, Đorđe T. AU - Petrović, Rada PY - 2017 UR - https://vinar.vin.bg.ac.rs/handle/123456789/1349 AB - The magnetic nanocomposites (MNCs), used as adsorbents for Cd2+ ions, were prepared by a co-precipitation method using both the untreated natural (SEP) and the partially acid-activated (ASEP) sepiolites as supports for magnetite. The synthesis conditions differed as follows: NaOH or NH3 was added in the SEP or the ASEP suspension before or after the addition of Fe3 and Fe2+. The SEP-based MNCs prepared using NaOH had a lower magnetization, but higher adsorption capacities than the MNCs synthesized using NH3. The order of the mixing of the reagents had a small influence on the properties of SEP-based MNCs, especially when NaOH was used for the synthesis. Due to acidity of the surface functional groups of the ASEP, the magnetic composite could be synthesized only when NH3 was added in the suspension of ASEP having Fe3+ and Fe2+ ions. Despite of the worse dispersibility of the magnetic particles, the adsorption capacityof the ASEP-based composite was higher than of the MNC with SEP prepared by the same procedure. All the MNCs showed a superparamagnetic behavior at room temperature and the adsorption capacities were higher than of pure compounds. The adsorption of Cd2+ on the composites was best fitted with the Sips model, which suggested the chemisorption on the heterogeneous surface at energetically non-uniform sites until a monolayer was formed. (C) 2016 Elsevier B.V. All rights reserved. T2 - Powder Technology T1 - Influence of the synthesis parameters on the properties of the sepiolite-based magnetic adsorbents VL - 305 SP - 260 EP - 269 DO - 10.1016/j.powtec.2016.09.086 ER -
@article{ author = "Ahribesh, Aysha Ali and Lazarevic, Slavica and Jankovic-Častvan, Ivona and Jokić, Bojan M. and Spasojević, Vojislav and Radetić, Tamara and Janaćković, Đorđe T. and Petrović, Rada", year = "2017", abstract = "The magnetic nanocomposites (MNCs), used as adsorbents for Cd2+ ions, were prepared by a co-precipitation method using both the untreated natural (SEP) and the partially acid-activated (ASEP) sepiolites as supports for magnetite. The synthesis conditions differed as follows: NaOH or NH3 was added in the SEP or the ASEP suspension before or after the addition of Fe3 and Fe2+. The SEP-based MNCs prepared using NaOH had a lower magnetization, but higher adsorption capacities than the MNCs synthesized using NH3. The order of the mixing of the reagents had a small influence on the properties of SEP-based MNCs, especially when NaOH was used for the synthesis. Due to acidity of the surface functional groups of the ASEP, the magnetic composite could be synthesized only when NH3 was added in the suspension of ASEP having Fe3+ and Fe2+ ions. Despite of the worse dispersibility of the magnetic particles, the adsorption capacityof the ASEP-based composite was higher than of the MNC with SEP prepared by the same procedure. All the MNCs showed a superparamagnetic behavior at room temperature and the adsorption capacities were higher than of pure compounds. The adsorption of Cd2+ on the composites was best fitted with the Sips model, which suggested the chemisorption on the heterogeneous surface at energetically non-uniform sites until a monolayer was formed. (C) 2016 Elsevier B.V. All rights reserved.", journal = "Powder Technology", title = "Influence of the synthesis parameters on the properties of the sepiolite-based magnetic adsorbents", volume = "305", pages = "260-269", doi = "10.1016/j.powtec.2016.09.086" }
Ahribesh, A. A., Lazarevic, S., Jankovic-Častvan, I., Jokić, B. M., Spasojević, V., Radetić, T., Janaćković, Đ. T.,& Petrović, R.. (2017). Influence of the synthesis parameters on the properties of the sepiolite-based magnetic adsorbents. in Powder Technology, 305, 260-269. https://doi.org/10.1016/j.powtec.2016.09.086
Ahribesh AA, Lazarevic S, Jankovic-Častvan I, Jokić BM, Spasojević V, Radetić T, Janaćković ĐT, Petrović R. Influence of the synthesis parameters on the properties of the sepiolite-based magnetic adsorbents. in Powder Technology. 2017;305:260-269. doi:10.1016/j.powtec.2016.09.086 .
Ahribesh, Aysha Ali, Lazarevic, Slavica, Jankovic-Častvan, Ivona, Jokić, Bojan M., Spasojević, Vojislav, Radetić, Tamara, Janaćković, Đorđe T., Petrović, Rada, "Influence of the synthesis parameters on the properties of the sepiolite-based magnetic adsorbents" in Powder Technology, 305 (2017):260-269, https://doi.org/10.1016/j.powtec.2016.09.086 . .