Shape-dependent carbonized PANI-coated TiO2 nanocrystals and its use in the decomposition of organic pollutants
Аутори
Milošević, MilicaRadoičić, Marija
Ćirić-Marjanović, Gordana
Spasojević, Jelena
Vukoje, Ivana
Radosavljević, Aleksandra
Šaponjić, Zoran
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Differently-shaped TiO2 photo-nanocatalysts play a principal role in the remediation of environmental and pollution challenges considering their proven potential for treating organic contaminants in wastewaters [1]. However, increasing the photoactivity of TiO2 i.e. its optical response from UV into visible region is a constant challenge of many ongoing researchers [2]. An proceed towards this demand may be the creation of hybrid functional nanocomposites by coating the TiO2 nanocrystals (NCs) with electronically coupled conductive polymers (e.g., polyaniline (PANI), polypyrrole, etc.) [3]. By the carbonization process of mentioned conductive polymers at high temperatures, obtained final material possess carbon-like structure which impart additional properties [4]. Thus, the evolution of carbonized PANI (CPANI)- coated TiO2 NCs opens up the possibility for tailoring the photocatalyst with distinctive properties. This study implies development of new nanocomposites based on CPANI and co...lloidal TiO2 nanoparticles (NPs) (TPC) and CPANI and TiO2 nanotubes (NTs) (TTPC). Sol- gel and hydrothermal synthesis paths were used to obtain TiO2 NCs. The influence of their size and shape on the photocatalytic activity of formed carbonized nanocomposites was estimated. TPC and TTPC nanocomposites were synthesized according to the steps: 1) the non-carbonized PANI/TiO2 class was firstly prepared by the chemical oxidative polymerization of aniline with ammonium peroxydisulfate in the presence of TiO2 NPs or NTs and 2) the subsequent carbonization process was applied (650 °C). Developed hybrid nanocomposites were morphologically and structurally characterized by TEM measurements and Raman spectroscopy, while their functionality was estimated through the photocatalytic degradation processes of Methylene blue and Rhodamine B. All TPC and TTPC nanocomposites showed excellent photocatalytic properties, however, shape-depending of used TiO2 NCs.
Извор:
29th International Symposium on Analytical and Environmental Problems : Proceedings, 2023, 225-225Издавач:
- Szeged : University of Szeged
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200017 (Универзитет у Београду, Институт за нуклеарне науке Винча, Београд-Винча) (RS-MESTD-inst-2020-200017)
Напомена:
- 29th International Symposium on Analytical and Environmental Problems (November 13-14, 2023; Szeged, Hungary)
Колекције
Институција/група
VinčaTY - CONF AU - Milošević, Milica AU - Radoičić, Marija AU - Ćirić-Marjanović, Gordana AU - Spasojević, Jelena AU - Vukoje, Ivana AU - Radosavljević, Aleksandra AU - Šaponjić, Zoran PY - 2023 UR - https://vinar.vin.bg.ac.rs/handle/123456789/12197 AB - Differently-shaped TiO2 photo-nanocatalysts play a principal role in the remediation of environmental and pollution challenges considering their proven potential for treating organic contaminants in wastewaters [1]. However, increasing the photoactivity of TiO2 i.e. its optical response from UV into visible region is a constant challenge of many ongoing researchers [2]. An proceed towards this demand may be the creation of hybrid functional nanocomposites by coating the TiO2 nanocrystals (NCs) with electronically coupled conductive polymers (e.g., polyaniline (PANI), polypyrrole, etc.) [3]. By the carbonization process of mentioned conductive polymers at high temperatures, obtained final material possess carbon-like structure which impart additional properties [4]. Thus, the evolution of carbonized PANI (CPANI)- coated TiO2 NCs opens up the possibility for tailoring the photocatalyst with distinctive properties. This study implies development of new nanocomposites based on CPANI and colloidal TiO2 nanoparticles (NPs) (TPC) and CPANI and TiO2 nanotubes (NTs) (TTPC). Sol- gel and hydrothermal synthesis paths were used to obtain TiO2 NCs. The influence of their size and shape on the photocatalytic activity of formed carbonized nanocomposites was estimated. TPC and TTPC nanocomposites were synthesized according to the steps: 1) the non-carbonized PANI/TiO2 class was firstly prepared by the chemical oxidative polymerization of aniline with ammonium peroxydisulfate in the presence of TiO2 NPs or NTs and 2) the subsequent carbonization process was applied (650 °C). Developed hybrid nanocomposites were morphologically and structurally characterized by TEM measurements and Raman spectroscopy, while their functionality was estimated through the photocatalytic degradation processes of Methylene blue and Rhodamine B. All TPC and TTPC nanocomposites showed excellent photocatalytic properties, however, shape-depending of used TiO2 NCs. PB - Szeged : University of Szeged C3 - 29th International Symposium on Analytical and Environmental Problems : Proceedings T1 - Shape-dependent carbonized PANI-coated TiO2 nanocrystals and its use in the decomposition of organic pollutants SP - 225 EP - 225 UR - https://hdl.handle.net/21.15107/rcub_vinar_12197 ER -
@conference{ author = "Milošević, Milica and Radoičić, Marija and Ćirić-Marjanović, Gordana and Spasojević, Jelena and Vukoje, Ivana and Radosavljević, Aleksandra and Šaponjić, Zoran", year = "2023", abstract = "Differently-shaped TiO2 photo-nanocatalysts play a principal role in the remediation of environmental and pollution challenges considering their proven potential for treating organic contaminants in wastewaters [1]. However, increasing the photoactivity of TiO2 i.e. its optical response from UV into visible region is a constant challenge of many ongoing researchers [2]. An proceed towards this demand may be the creation of hybrid functional nanocomposites by coating the TiO2 nanocrystals (NCs) with electronically coupled conductive polymers (e.g., polyaniline (PANI), polypyrrole, etc.) [3]. By the carbonization process of mentioned conductive polymers at high temperatures, obtained final material possess carbon-like structure which impart additional properties [4]. Thus, the evolution of carbonized PANI (CPANI)- coated TiO2 NCs opens up the possibility for tailoring the photocatalyst with distinctive properties. This study implies development of new nanocomposites based on CPANI and colloidal TiO2 nanoparticles (NPs) (TPC) and CPANI and TiO2 nanotubes (NTs) (TTPC). Sol- gel and hydrothermal synthesis paths were used to obtain TiO2 NCs. The influence of their size and shape on the photocatalytic activity of formed carbonized nanocomposites was estimated. TPC and TTPC nanocomposites were synthesized according to the steps: 1) the non-carbonized PANI/TiO2 class was firstly prepared by the chemical oxidative polymerization of aniline with ammonium peroxydisulfate in the presence of TiO2 NPs or NTs and 2) the subsequent carbonization process was applied (650 °C). Developed hybrid nanocomposites were morphologically and structurally characterized by TEM measurements and Raman spectroscopy, while their functionality was estimated through the photocatalytic degradation processes of Methylene blue and Rhodamine B. All TPC and TTPC nanocomposites showed excellent photocatalytic properties, however, shape-depending of used TiO2 NCs.", publisher = "Szeged : University of Szeged", journal = "29th International Symposium on Analytical and Environmental Problems : Proceedings", title = "Shape-dependent carbonized PANI-coated TiO2 nanocrystals and its use in the decomposition of organic pollutants", pages = "225-225", url = "https://hdl.handle.net/21.15107/rcub_vinar_12197" }
Milošević, M., Radoičić, M., Ćirić-Marjanović, G., Spasojević, J., Vukoje, I., Radosavljević, A.,& Šaponjić, Z.. (2023). Shape-dependent carbonized PANI-coated TiO2 nanocrystals and its use in the decomposition of organic pollutants. in 29th International Symposium on Analytical and Environmental Problems : Proceedings Szeged : University of Szeged., 225-225. https://hdl.handle.net/21.15107/rcub_vinar_12197
Milošević M, Radoičić M, Ćirić-Marjanović G, Spasojević J, Vukoje I, Radosavljević A, Šaponjić Z. Shape-dependent carbonized PANI-coated TiO2 nanocrystals and its use in the decomposition of organic pollutants. in 29th International Symposium on Analytical and Environmental Problems : Proceedings. 2023;:225-225. https://hdl.handle.net/21.15107/rcub_vinar_12197 .
Milošević, Milica, Radoičić, Marija, Ćirić-Marjanović, Gordana, Spasojević, Jelena, Vukoje, Ivana, Radosavljević, Aleksandra, Šaponjić, Zoran, "Shape-dependent carbonized PANI-coated TiO2 nanocrystals and its use in the decomposition of organic pollutants" in 29th International Symposium on Analytical and Environmental Problems : Proceedings (2023):225-225, https://hdl.handle.net/21.15107/rcub_vinar_12197 .