Organic solvents review for sulphur-dioxide absorption from flue gases for regenerative processes with physical absorption
Само за регистроване кориснике
2016
Конференцијски прилог (Објављена верзија)
Метаподаци
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In addition to lime / limestone process, the most common procedure for sulfur-dioxide (SO2) removal from flue gases, separation processes with physical absorption and liquid organic solvent thermal regeneration recently gained importance. Organic liquid solvent selection, ahead of other process parameters, is crucial for process separation efficiency, in terms of the amount of SO2 absorbed by the solvent. The paper presents literature review and analysis of SO2 solubility in currently used and potential liquid organic solvents, polyethylene glycols (PEG 200 and PEG 400), tetraethylene glycol dimethyl ether (TEGDME), 1-methyl-2-pyrrolidone (NMP) as well as their binary mixtures with other components. The solvents in question bind SO2 by physical absorption mechanism, with the exception of NMP which binds SO2 by two parallel mechanisms, physical and chemical absorption. Research have even shown that mixtures of physical and chemical solvents or presence of both absorption mechanisms some...times show better characteristics regarding binding capacity and selectivity. The importance of ionic liquids, as future solvents for separation processes, is particularly highlighted, due to their favorable thermophysical properties.
Pored najrasprostranjenijeg, krečnjačkog postupka, za uklanjnje sumpor-dioksida (SO2) iz dimnih gasova, u novije vreme sve veći značaj dobijaju separacioni postupci sa fizičkom apsorpcijom i termičkom regeneracijom tečnog organskog solventa. Izbor solventa, ispred drugih procesnih parametara, ključan je za efikasnost procesa u pogledu stepena izdvajanja SO2. U radu je dat literaturni pregled i analiza rastvoljivosti SO2 u trenutno korišćenim i potencijalnim tečnim organskim solventima, polietilen glikolima (PEG 200 i PEG 400), tetraetilen glikol dimetil etru (TEGDME), 1-metil-2-pirolidonu (NMP) i za njihove binarne smeše sa drugim komponentama. Razmatrani solventi vezuju SO2 mehanizmom fizičke apsorpcije, sa izuzetkom NMP-a kod koga su prisutna dva paralelna mehanizma, fizička i hemijska apsorpcija. Istraživanja su čak pokazala da smeše fizičkih i hemijskih solvenata ili smeše u kojima su prisutni mehanizmi i fizičke i hemijska apsorpcije ponekad pokazuju bolje karaktristike u pogledu ...stepena izdvajanja i selektivnosti. Posebno je istaknut značaj jonskih tečnosti kao solvenata budućnosti za separacione proces, zbog svojih povoljnih termofizičkih svojstava.
Кључне речи:
sulfur dioxid / organic solvents / physical absorption / solubility / ionic liquids / sumpor-dioksid / organski solventi / fizička apsorpcija / rastvorljivost / jonske tečnostiИзвор:
Power Plants 2016 : Proceeding of International Conference, 2016, 896-905Финансирање / пројекти:
- Смањење аерозагађења из термоелектрана у ЈП Електропривреда Србије (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-42010)
- Побољшање квалитета и технологије сагоревања домаћих лигнита у циљу повећања енергетске ефикасности и смањења емисије штетних материја из термоелектрана ЈП Електропривреда Србије (RS-MESTD-Technological Development (TD or TR)-33050)
Напомена:
- Power Plants 2016 : Proceeding of International Conference; November 23-26, 2016, Zlatibor, Serbia
Колекције
Институција/група
VinčaTY - CONF AU - Živković, Nikola AU - Stefanović, Predrag AU - Kijevčanin, Mirjana AU - Živković, Emila AU - Spasojević, Vuk PY - 2016 UR - https://vinar.vin.bg.ac.rs/handle/123456789/12114 AB - In addition to lime / limestone process, the most common procedure for sulfur-dioxide (SO2) removal from flue gases, separation processes with physical absorption and liquid organic solvent thermal regeneration recently gained importance. Organic liquid solvent selection, ahead of other process parameters, is crucial for process separation efficiency, in terms of the amount of SO2 absorbed by the solvent. The paper presents literature review and analysis of SO2 solubility in currently used and potential liquid organic solvents, polyethylene glycols (PEG 200 and PEG 400), tetraethylene glycol dimethyl ether (TEGDME), 1-methyl-2-pyrrolidone (NMP) as well as their binary mixtures with other components. The solvents in question bind SO2 by physical absorption mechanism, with the exception of NMP which binds SO2 by two parallel mechanisms, physical and chemical absorption. Research have even shown that mixtures of physical and chemical solvents or presence of both absorption mechanisms sometimes show better characteristics regarding binding capacity and selectivity. The importance of ionic liquids, as future solvents for separation processes, is particularly highlighted, due to their favorable thermophysical properties. AB - Pored najrasprostranjenijeg, krečnjačkog postupka, za uklanjnje sumpor-dioksida (SO2) iz dimnih gasova, u novije vreme sve veći značaj dobijaju separacioni postupci sa fizičkom apsorpcijom i termičkom regeneracijom tečnog organskog solventa. Izbor solventa, ispred drugih procesnih parametara, ključan je za efikasnost procesa u pogledu stepena izdvajanja SO2. U radu je dat literaturni pregled i analiza rastvoljivosti SO2 u trenutno korišćenim i potencijalnim tečnim organskim solventima, polietilen glikolima (PEG 200 i PEG 400), tetraetilen glikol dimetil etru (TEGDME), 1-metil-2-pirolidonu (NMP) i za njihove binarne smeše sa drugim komponentama. Razmatrani solventi vezuju SO2 mehanizmom fizičke apsorpcije, sa izuzetkom NMP-a kod koga su prisutna dva paralelna mehanizma, fizička i hemijska apsorpcija. Istraživanja su čak pokazala da smeše fizičkih i hemijskih solvenata ili smeše u kojima su prisutni mehanizmi i fizičke i hemijska apsorpcije ponekad pokazuju bolje karaktristike u pogledu stepena izdvajanja i selektivnosti. Posebno je istaknut značaj jonskih tečnosti kao solvenata budućnosti za separacione proces, zbog svojih povoljnih termofizičkih svojstava. C3 - Power Plants 2016 : Proceeding of International Conference T1 - Organic solvents review for sulphur-dioxide absorption from flue gases for regenerative processes with physical absorption SP - 896 EP - 905 UR - https://hdl.handle.net/21.15107/rcub_vinar_12114 ER -
@conference{ author = "Živković, Nikola and Stefanović, Predrag and Kijevčanin, Mirjana and Živković, Emila and Spasojević, Vuk", year = "2016", abstract = "In addition to lime / limestone process, the most common procedure for sulfur-dioxide (SO2) removal from flue gases, separation processes with physical absorption and liquid organic solvent thermal regeneration recently gained importance. Organic liquid solvent selection, ahead of other process parameters, is crucial for process separation efficiency, in terms of the amount of SO2 absorbed by the solvent. The paper presents literature review and analysis of SO2 solubility in currently used and potential liquid organic solvents, polyethylene glycols (PEG 200 and PEG 400), tetraethylene glycol dimethyl ether (TEGDME), 1-methyl-2-pyrrolidone (NMP) as well as their binary mixtures with other components. The solvents in question bind SO2 by physical absorption mechanism, with the exception of NMP which binds SO2 by two parallel mechanisms, physical and chemical absorption. Research have even shown that mixtures of physical and chemical solvents or presence of both absorption mechanisms sometimes show better characteristics regarding binding capacity and selectivity. The importance of ionic liquids, as future solvents for separation processes, is particularly highlighted, due to their favorable thermophysical properties., Pored najrasprostranjenijeg, krečnjačkog postupka, za uklanjnje sumpor-dioksida (SO2) iz dimnih gasova, u novije vreme sve veći značaj dobijaju separacioni postupci sa fizičkom apsorpcijom i termičkom regeneracijom tečnog organskog solventa. Izbor solventa, ispred drugih procesnih parametara, ključan je za efikasnost procesa u pogledu stepena izdvajanja SO2. U radu je dat literaturni pregled i analiza rastvoljivosti SO2 u trenutno korišćenim i potencijalnim tečnim organskim solventima, polietilen glikolima (PEG 200 i PEG 400), tetraetilen glikol dimetil etru (TEGDME), 1-metil-2-pirolidonu (NMP) i za njihove binarne smeše sa drugim komponentama. Razmatrani solventi vezuju SO2 mehanizmom fizičke apsorpcije, sa izuzetkom NMP-a kod koga su prisutna dva paralelna mehanizma, fizička i hemijska apsorpcija. Istraživanja su čak pokazala da smeše fizičkih i hemijskih solvenata ili smeše u kojima su prisutni mehanizmi i fizičke i hemijska apsorpcije ponekad pokazuju bolje karaktristike u pogledu stepena izdvajanja i selektivnosti. Posebno je istaknut značaj jonskih tečnosti kao solvenata budućnosti za separacione proces, zbog svojih povoljnih termofizičkih svojstava.", journal = "Power Plants 2016 : Proceeding of International Conference", title = "Organic solvents review for sulphur-dioxide absorption from flue gases for regenerative processes with physical absorption", pages = "896-905", url = "https://hdl.handle.net/21.15107/rcub_vinar_12114" }
Živković, N., Stefanović, P., Kijevčanin, M., Živković, E.,& Spasojević, V.. (2016). Organic solvents review for sulphur-dioxide absorption from flue gases for regenerative processes with physical absorption. in Power Plants 2016 : Proceeding of International Conference, 896-905. https://hdl.handle.net/21.15107/rcub_vinar_12114
Živković N, Stefanović P, Kijevčanin M, Živković E, Spasojević V. Organic solvents review for sulphur-dioxide absorption from flue gases for regenerative processes with physical absorption. in Power Plants 2016 : Proceeding of International Conference. 2016;:896-905. https://hdl.handle.net/21.15107/rcub_vinar_12114 .
Živković, Nikola, Stefanović, Predrag, Kijevčanin, Mirjana, Živković, Emila, Spasojević, Vuk, "Organic solvents review for sulphur-dioxide absorption from flue gases for regenerative processes with physical absorption" in Power Plants 2016 : Proceeding of International Conference (2016):896-905, https://hdl.handle.net/21.15107/rcub_vinar_12114 .